Synthesis and Characterization of Sodium Dodecyl Sulphate Intercalated Zirconium Phosphate (SDS-ZrP): A New Zinc Selective Ion- exchange Material
Arshid Bashir and Altaf Hussain Pandith
Herein, we report the synthesis of surfactant based sodium dodecyl sulphate zirconium phosphate (SDS-ZrP) intercalated cation exchange material. The material was characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy(SEM), powder X-ray diffraction(XRD), thermo gravimetric analysis(TGA) and differential thermal gravimetry (DTG). The synthesized composite material showed good ion exchange capacity of 3.11 mequiv g-1 for strontium ion. Ion-exchange studies on the synthesized material have also been performed for heavy metal ions in neutral and acidic media .The composite exhibited high selectivity towards Zn (II) with distribution coefficient value of 4900mLg^(-1). The presence of surfactant in the matrix of composite highly enhances its adsorption capacity towards heavy metal ions. On the basis of significant dimensionless separation factor (SF) in a particular media, some binary separations of Zn (II) ion from other heavy metal ions were performed on the column loaded with SDS-ZrP.
Sodium dodecyl sulphate, Ion exchange material, Zirconium phosphate
Published online 11/1/2016, 20 pages
Part of New Polymeric Composite Materials
 D.V. Marinin, G.N. Brown, Studies of sorbent/ ion exchange materials for the removal of radioactive strontium from liquid radioactive waste and high hardness ground waters, Waste Manag. 20 (2000) 545–553.
 B. Preetha, C. Jonardanan, Ion exchange method for the detection of trace amounts of Mn2+ using nano cerium zirconium phosphate cation exchanger, Ion Exch. Lett. 3 (2010) 12-18.
 R. Chitrakar, S. Tezuka , A. Sonoda, K. Sakane, K. Ooi, T. Hirotsu, Selective adsorption of phosphate from sea water and waste water by amorphous zirconium hydroxide, J. Coll. Interf. Sci. 297 (2006) 426-433.
 V.N. Lebedev, N.A. Melnik, A.V. Rudenko, Sorption of cesium on titanium and zirconium phosphates, Radiochemistry. 45 (2003) 149-151.
 K.G. Varshney , A. H. Pandith ,U. Gupta, Synthesis and characterization of zirconium alumino phosphate. A new cation esxchanger,Langmuir. 14 (1998) 7353-58.
 K.G. Varshney, A.H. Pandith, Foreward and reverse ion –exchange kinetics for some alkali and akaline earth metal ions on amorphous zirconium (IV)alumino phosphate, Langmuir. 15(1999) 7422-25.
 S.D. Ajagekar, Z.R. Turel, Selective adsorption and radiochemical separation of Sr (II) using zirconium phosphate ion exchanger, J. Ind. Council. Chem. 26 (2010) 187-189.
 M.A. Hafez, I.M. Kenway, M.A. Akl, R.R. Lashein, Preconcentration and separation of total mercury in environmental samples using chemically modified chloromethylated polystyrene-PAN (ion-exchanger) and its determination by cold vapour atomic absorption spectrometry,Talanta. 53(2001) 749-760.
 M. Nushad, R. Mitra, J, Raguvanshi, Use of neutral red modified strong acid cation exchange resin for separation of heavy metal ions, Ion Exch. Lett. 2 (2009) 31-34.
 Inamuddin, S.A. Khan, W.A. Siddiqui, A.A. Khan, Synthesis, characterization and ion-exchange properties of a new and novel organic–inorganic hybrid cation exchanger : Nylon-6,6, Zr(IV) phosphate, Talanta. 71 (2007) 841–847.
 K.G. Varshney, A.H. Pandith, Synthesis and ion exchange behavior of acrylonitrile based zirconium-phosphate; a new hybrid ion-exchanger, J. Indian Chem. Soc. 78 (2001) 250-253.
 A.Somya, M.Z.A. Rafiquee, K.G. Varshney, Synthesis, characterization and analytical applications of sodium dodecyl sulphate cerium (IV) phosphate: A new Pb (II) selective, surfactant-based intercalated fibrous ion exchanger, Colloid Surf. A: Physiochem. Eng. Asp. 336 (2009) 142–146.
 A.A Khan, Inamuddin, Cation-exchange kinetics and electrical conductivity studies of an organic-inorganic composite cation-exchanger: polypyroleTh(IV) phosphate, J. Appl. Polym. Sci. 105(2007) 2806 – 2815.
 S. Rehman, N. Islam, S.Ahad, S.Z. Fatima, A. H.Pandith, Preparation and characterization of 5-sulphosalicylic acid doped tetraethoxysilane composite ion-exchange material by sol–gel method. J. Hazard. Mat. 260 (2013) 313 – 322.
 H. Patel, A. Parikh, U. Chudasama, A comparative study of proton transport properties of metal (IV) tungstates and their organic derivatives, Bull. Mater. Sci. 28(2005) 137-144.
 A. Khan, A. M. Asiri, M.A. Rub, N. Azum, A.S.P. Khan, Khan, P.K. Mondal, Review on composite cation exchanger as interdisciplinary materials in analytical chemistry, Int. J. Electrochem. Sci. 7(2012) 3854-3902.
 A. Shahat, M.R. Awual, M. Naushad, Functional ligand anchored nanomaterial based facial adsorbent for cobalt(II) detection and removal from water samples. Chem Eng J 271 (2015) 155-163.
 S.A. Nabi, A.H. Shalla, EDTA-stannic (IV) iodate: preparation, characterization and its analytical applications for metal content determination in real and synthetic samples, J Porous Mater. 16 (2009) 587-597.
 B.C. Pan, Q.R. Zhang, W. Du, Q.J. Zhang, Selective removal of heavy metals from water by zirconium phosphate; behavior and mechanism, Water Res. 41(2007) 3103-3111.
 T. Kijima and Y.Matsui, A new type of host compound consisting of α-zirconium phosphate and an amminatedcyclodextrin, Nature, 322 (1986) 533 – 534.
 R. Thakkar, H. Patel, U. Chudasma, A comparative study of proton transport properties of zirconium phosphate and its metal exchanged phases, Bull. Mater. Sci. 30 (2007) 205-209.
 A.A. Khan, T. Akhtar, Preparation, physio-chemical characterization and electrical conductivity measurement studies of an organic-inorganic nano-composite cation exchanger: poly-o-toluidine Zr(IV) phosphate, Electrochim. Acta. 53(2008) 5540-5548.
 J. Wang, Y. Hua, B. Li, Z. Guia, Z. Chen, Preparation of polyacrylamide and gamma-zirconium phosphate nanocomposites by intercalative polymerization, UltrasonicsSonochemistry. 11 (2004) 301–306.
 L. Wang, X. Wu, W. Xu, X. Huang, J. Liu, and A. Xu, Stable Organic−inorganic hybrid of polyaniline/α-zirconium phosphate for efficient removal of organic pollutants in water environment, Appl. Mater. Interfaces.4 (2012)2686−2692.
 V.K. Gupta, Deepak Pathania, N.C. Kothiyal, G. Sharma, Polyaniline zirconium(IV) silicophosphate nanocomposite as absorbent for removal of methylene blue dye from water system, J. Mol. Liq. 190 (2014) 139-145.
 K.G. Varshney and A. H.Pandith, Synthesis and characterization of styrene supported zirconium phosphate; A new ion- exchange material, J. Chem and Env. Res. 5 (1996)1-4.
 M.H.H. Alhendawi, Synthesis and structural characterization of a new chiral porous hybrid organic–inorganic material based zirconium phosphates and L-(+)-phosphoserine, J.Solid State Chem.201 (2013) 24-28.
 W. A. Siddiqui, S.A. Khan, Inamuddin, Synthesis, characterization and ion- exchange properties of a new and novel ‘organic–inorganic hybrid’cation-exchanger Poly (methylene methacrylate) Zr(IV)phosphate, Colloid Surf. A: Physiochem. Eng. Asp. 295 (2007) 193–199.
 Y.Zhou, R. Huang, F.Ding, D. A. Brittain, J. Liu, M. Zhang, M. Xiao, Y. Meng, and L. Sun, Sulfonic acid-functionalized α‑zirconium phosphate single-layer nanosheets as a strong solid acid for heterogeneous catalysis applications, J.Appl. Mater.Interfaces.6 (2014) 7417−7425.
 V.K. Gupta, D. Pathania, P. Singh, B. S. Rathore, P. Chauhan, Cellulose acetate–zirconium (IV) phosphate nano-composite with enhanced photo-catalytic activity, Carbohydrate Polym. 95 (2013) 434–440.
 Q. Zhang, B. Pan, W.M. Zhang and K.Jia, Selective sorption of lead, cadmium and zinc ions by a polymeric cation exchanger containing nano‐Zr (HPO3S)2, J. Environ. SciTechnol . 42(2008) 4140–4145.
 T. K. Sen and M. V. Sarzali, Removal of cadmium metal ion Cd2+ from its aqueous solution by aluminium oxide: A kinetic and equilibrium study, J. Chem. Eng. 142 (2008) 256-262.
 F. Arias and T. K. Sen, Removal of zinc metal ion (Zn2+) from its aqueous solution by kaolin clay mineral: A kinetic and equilibrium study, Colloid Surf. A, 348 (2009) 100-108.
 C. H. Weng and C. P. Huang, Adsorption characteristics of Zn (II) from dilute aqueous solutions by fly ash, Colloids Surf. A. 247 (2004) 137-143.
 D. Mohan and K. P. Singh, Single and multi-component adsorption of cadmium and zinc using activated carbon derived from bagasse-an agricultural waste, Water Res.36 (2002) 2304-2318.
 A. K. Bhattacharya, S. N. Mandal and S. K. Das, Adsorption of Zn (II) from aqueous solution by using different adsorbents, J. Chem. Eng. 123 (2006) 43-51.
 S. A. Nabi, R. Bushra, Z. A. Al-Othman & Mu.Naushad, Synthesis, characterization, and analytical aplications of a new composite cation exchange material acetonitrile stannic(IV) selenite: adsorption behavior of toxic metal ions in nonionic surfactant medium, J. Sep. Sci. and Tech. 46 (2011)847–857.
 K.G. Varshney, M.Z.A. Rafiquee, A Somya, M. Drabik, Synthesis and characterization of Hg(II) selective n-butylacetate cerium(IV) phosphate as a new intercalated fibrous ion exchanger: Effect of surfactants on the adsorption behavior, Ind. J. Chem. A. 45 (2006) 1856-1860.
 J.A. Loughlin and L. S. Romsted. A new method for estimating counter-ion selectivity of a cationic association colloid: trapping of interfacial chloride and bromide counter-Ions by reaction with micellar bound aryldiazonium Salts, Colloids and Surf. 48 (1990) 123-137.
 M. Naushad, Z.A. ALOthman, Inamuddin, H. Javadian, Removal of Pb(II) from aqueous solution using ethylene diamine tetra acetic acid-Zr(IV) iodate composite cation exchanger: Kinetics, isotherms and thermodynamic studies.J Ind Eng Chem 25 (2015) 35-41.
 E.V. Bakhmotava, O. Zhiang, D.G. Medevdev, A. Clearfield, Cobalt phosphonates: an unusual cobalt polymeric phosphonate containing a clathrated phosphonate anion and a layered bisphosphonate, J. Inorg. Chem. 42 (2003) 7046-7051.
 H.C. Yang, K. Aoki, H.G. Hong, D.D. Sackett, Growth and characterization of metal(II) alkane bisphosphonate multilayer thin films on gold surfaces, J. Am. Soc. 115 (1993)11855-11862.
 G. Alberti, U. Constantino, R. Millini, G. Perego, R.Vivan, Preparation, characterization and structure of α-zirconium hydrogen phosphate hemihydrates, J. Solid State Chem.113(1994) 289-295.
 F.C. Nachod, W. Wood, The reaction velocity of ion exchange, J. Am. Chem. Soc. 66(1944) 1380-1384.
 S.A. Nabi, A.H. Shalla, A.M. Khan, S.A. Ganie, Synthesis, characterization and analytical applications of titanium( IV) molybdosilicate: a cation ion-exchanger, J. Coll. Surf. 203(2007) 241-250.
 M. Naushad, Z.A. ALOthman, M.M. Alam, M.R. Awual, Sol-gel synthesis of sodium dodecyl sulphate supported nanocomposite cation exchanger: Removal and recovery of Cu2+ from synthetic, pharmaceutical and alloy samples.Iran J Chem12 (2015) 1677-1686
 M. Naushad, Inamuddin, T.A. Rangreez, Potentiometric determination of Cd(II) ions using PVC based polyaniline Sn(IV) silicate composite cation exchanger ion selective membrane electrode. Des & Water Treat 55 (2015) 463-470.