Recycled smelter slag as an engineering material – opportunity and sustainability

Recycled smelter slag as an engineering material – opportunity and sustainability

Saidur R. Chowdhury

download PDF

Abstract. Slags obtained from the Vale Copper Cliff smelter in Sudbury, Ontario, Canada, were investigated as sustainable engineering materials in this study. The recycled smelter waste products can remove toxic contaminants from the aqueous environment as well as be used in the construction industry (as aggregates, cement admixtures, filling materials), soil improvement for agricultural purposes, and other value-added applications and products. The removal mechanisms of the heavy metals (such as Zn, Pb, and Cu, etc.) from aqueous solutions could be physical or chemical adsorption, ion exchange, oxidation-reduction, etc. At the same time, using recycled smelter slags in various engineering applications can help with waste reduction, disposal cost reduction, resource recovery, and increased reused activities. The present study helps explore the scope of using recycled materials in the treatment or construction industry. Using industrial smelter slag as a recycling or renewable resource rather than a waste product has environmental and economic benefits. The study also specifically discusses Ni smelter slag’s composition, application, treatment efficiency, opportunity, economic benefits, and circularity for sustainable management.

Keywords
Slag, Adsorbent, Construction, Recycling, Nickel (Ni)

Published online 8/10/2023, 10 pages
Copyright © 2023 by the author(s)
Published under license by Materials Research Forum LLC., Millersville PA, USA

Citation: Saidur R. Chowdhury, Recycled smelter slag as an engineering material – opportunity and sustainability, Materials Research Proceedings, Vol. 31, pp 194-203, 2023

DOI: https://doi.org/10.21741/9781644902592-21

The article was published as article 21 of the book Advanced Topics in Mechanics of Materials, Structures and Construction

Content from this work may be used under the terms of the Creative Commons Attribution 3.0 license. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.

References
[1] T.C. Nguyen, P. Loganathan, T.V. Nguyen, J. Kandasamy, R. Naidu, R., S.Vigneswaran, Adsorptive removal of five heavy metals from water using blast furnace slag and fly ash’. Environ Sci. Pollut. Res. 25 (2008), 20430–20438. https://doi.org/10.1007/s11356-017-9610-4
[2] A.K. Thakur, T.R. Singh, R.T. Pullela, V. Pundir, Green adsorbents for the removal of heavy metals from Wastewater: A review. Materials Today: Proceedings, (2021), https://doi.org/10.1016/j.matpr.2021.11.373
[3] S.D. Gisi, G. Lofrano, M. Grassi, M. Notarnicola, Characteristics and adsorption capacities of low-cost sorbents for wastewater treatment: A review. Sustainable Materials and Technologies 9 (2016) 10–40.
[4] M. Oge, D. Ozkan, M.B. Celik, M.S. Gok, A.C. Karaoglanli, An Overview of Utilization of Blast Furnace and Steelmaking Slag in Various Applications. Materials Today: Proceedings 11 (2019) 516–525.
[5] I. Perederiy, Dissolution of Valuable Metals from Nickel Smelter Slags by Means of High Pressure Oxidative Acid Leaching. PhD Thesis. Department of Chemical Engineering and Applied Chemistry University of Toronto (2011).
[6] R. Chakraborty, A. Asthana, A.K. Singh, B. Jain, A.B.H. Susan, Adsorption of heavy metal ions by various low-cost adsorbents: a review. International Journal of Environmental Analytical Chemistry 102,(2), (2022) https://doi-org.library.pmu.edu.sa/10.1080/03067319.2020.1722811.
[7] H.K. Boparai, M. Joseph, and D.M. Carroll, Kinetics and thermodynamics of cadmium ion removal by adsorption onto nano zerovalent. J. Hazmat. 186(1), (2011) 458-65 https://doi.org/10.1016/j.jhazmat.2010.11.029
[8] D. Feng, C. Aldrich, H. Tan, H, Treatment of acid mine water by use of heavy metal precipitation and ion exchange. Minerals Engineering, 13(6), (2000)623-642.
[9] S. Liu, J. Gao, Y. Yang, Y. Yang, and Z. Ye, Adsorption intrinsic kinetics and isotherms of lead ions on steel slag. Journal of Hazardous Materials, 173(1–3), (2010)558-562. https://doi.org/http://dx.doi.org/10.1016/j.jhazmat.2009.08.122
[10] S.R. Chowdhury, E.K. Yanful, and A.R. Pratt, Recycling of nickel smelter slag for arsenic remediation – an experimental study’. Environmental Science and Pollution Research. 21, (17), (2014)10096- 10107.
[11] S.R. Chowdhury, Application of mixed iron oxides in subsurface remediation technologies. London, Ont.: School of Graduate and Postdoctoral Studies, University of Western Ontario. Canada (2013).
[12] F.Y. Wang, H.Wang, J.W. Ma, Adsorption of cadmium (II) ions from aqueous solution by a new low-cost adsorbent—Bamboo charcoal’. Journal of Hazardous Materials 177, (2010) 300–306.
[13] Ahmaruzzaman, M. Industrial wastes as low-cost potential adsorbents for the treatment of wastewater laden with heavy metals. Advances in Colloid and Interface Science, 166(1–2), (2011) 36-59. https://doi.org/http://dx.doi.org/10.1016/j.cis.2011.04.005.
[14] G. McKay, M.S. Otterburn, and A.G. Sweeney, Surface mass transfer processes during colour removal from effluent using silica. Water Research, 15 (1980), 327-331.
[15] Y. Chen, W. Ye, M. Yang, H. Yong, Effect of contact time, pH, and ionic strength on Cd (II) adsorption from aqueous solution onto bentonite from Gaomiaozi, China. Environmental Earth Sciences 64(2) (2011): 329-336.
[16] D.L. Sparks, Environmental soil chemistry. Amsterdam; Boston: Academic Press. 2003.
[17] S.K. Srivastava, V.K. Gupta, D. Mohan, Removal of lead and chromium by activated slag-a blast-furnace waste. J Environ. Eng. 123(5) (1997):461–46
[18] Y. Zhou, and R.J. Haynes, Sorption of heavy metals by inorganic and organic components of solid wastes: Significance to use of wastes as low-cost adsorbents and immobilizing agents’. Critical Reviews in Environmental Science and Technology, 40(11), (2010) 909- 977. https://doi.org/10.1080/10643380802586857
[19] Q. Zhao, L. Pang, D. Wang, Adverse Effects of Using Metallurgical Slags as Supplementary Cementitious Materials and Aggregate: A Review. Materials 15 (2022) 3803. https://doi.org/10.3390/ ma15113803
[20] M. Czop, and B.L. Piekarczyk, Use of Slag from the Combustion of Solid Municipal Waste as A Partial Replacement of Cement in Mortar and Concrete. Materials, 13 (2020), 1593; https://doi.org/10.3390/ma13071593
[21] H. Yi, G. Xu, H. Cheng, J. Wang, Y. Wan, H. Chen, An overview of utilization of steel slag. Procedia Environmental Sciences 16 (2012) 791 – 801.
[22] Q. Wanga, P.Y. Yana, J.W. Feng, A discussion on improving hydration activity of steel slag by altering its mineral compositions. J. Hazard Mater.186(2011)1070-1075.
[23] H. Qasrawi, F. Shalabi, I. Asi, Use of low CaO unprocessed steel slag in concrete as aggregate. Constr Build Mater 23 (2009)1118-1125.
[24] I. Papayianni, E. Anastasiou, Production of high-strength concrete using high volume of industrial by-products. Constr Build Mater, 24 (2010),1412-7.
[25] Z.H. Wu, Z.S. Zou, C.Z. Wang, Application of converter slags in agriculture. Multipurpose Util Min Resour (in Chinese), 6 (2005), 25-8.
[26] Y. Sun, M.S. Yao, J.P. Zhang, G. Yang, Indirect CO2 mineral sequestration by steelmaking slag with NH4Cl as leaching solution. Chem Eng J.173 (2011), 437-445.
[27] S. Eloneva, S. Tei, J. Salminen, C.J. Fogelholma, R. Zevenhoven. Fixation of CO2 by carbonating calcium derived from blast furnace slag. Energ. 33 (2008)1461-7.
[28] C. Kunzler, N. Alves, E. Pereira, J. Nienzewksi, R. Ligabue, S. Einloft, et al., CO2 storage with indirect carbonation using industrial waste. Energ Procedia, 4 (2011)1010-7.
[29] E.E. Changa, S.Y. Panb, Y.H. Chen, H.W. Chu, C.F. Wang, P.C. Chiang, CO2 sequestration by carbonation of steelmaking slags in an autoclave reactor. J Hazard Mater. 195 (2011) 107-114.
[30] Y. Sun, M.S. Yao, J.P. Zhang, G. Yang. Indirect CO2 mineral sequestration by steelmaking slag with NH4Cl as leaching solution. Chem Eng J. 173 (2011) 437-445.
[31] S.R. Chowdhury, E.K. Yanful, Application of recycling waste products for exsitu and in situ water treatment methods’. Environmental Technology, 41 (2020) (7), 878-889. https://doi.org/10.1080/09593330.2018.1513078
[32] S.R. Chowdhury, Recycled Smelter Slags for In Situ and Ex Situ Water and Wastewater Treatment— Current Knowledge and Opportunities. Processes 11 (2023), 783. https://doi.org/10.3390/pr11030783