Removal of phosphates and sulphates in a multi-ion system with nitrates

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Removal of phosphates and sulphates in a multi-ion system with nitrates

Patricia A. Terry, Megan Olson Hunt, Renee Henning

Eutrophication remains a water quality issue globally, and evidence demonstrates that sulphates in water may interact to release phosphates bound in underlying soil sediments, such that removal of aqueous phosphate may not be adequate to eliminate eutrophication. Further, sulphates promote the formation of cyanobacteria, which creates potentially toxic conditions in affected waterways. This work characterises the effect of phosphates, sulphates, and nitrates on the co-removal of phosphates and sulphates from contaminated water via ion exchange with calcined hydrotalcite, a clay mineral double layer hydroxide. To assess the statistical significance of main effects and interactions between anions on mean residual target anion levels, fixed-effects two- and three-way analyses of variance were used. Langmuir isotherms for single-ion removal are estimated and compared to those for ternary solutions at phosphate, sulphate, and nitrate levels typical for contaminated ground and surface waters. For phosphate removal in the ternary system, the two-way interactions between sulphate and initial phosphate, and between sulphate and nitrate were statistically significant. However, phosphate removal remained high – between 94 and 99% – in all cases, demonstrating that this is a viable removal method. Sulphate removal was also dictated by significant interactions (two- and three-way), but, as with phosphate, the reduction was still successful in general. The findings indicate that while high sulphate levels may not be removed sufficiently so as to prevent eutrophication if phosphates are held in soil sediments, for intermediate and low levels of sulphate, hydrotalcite is a useful material for the co-removal of phosphate and sulphate in eutrophic waters.

Keywords
Ion Exchange, Hydrotalcite, Phosphate Removal, Nitrate, Langmuir Isotherm

Published online 4/25/2017, 22 pages
Copyright © 2016 by the author(s)
Published under license by Materials Research Forum LLC., Millersville PA, USA

Citation: Patricia A. Terry, Megan Olson Hunt, Renee Henning, ‘Removal of phosphates and sulphates in a multi-ion system with nitrates’, Materials Research Foundations, Vol. 15, pp 171-192, 2017

DOI: http://dx.doi.org/10.21741/9781945291333-7

The article was published as article 7 of the book Applications of Adsorption and Ion Exchange Chromatography in Waste Water Treatment

References
[1] Adam, K., A. K. Sovik, and T. Krogstad (2006) Sorption of phosphorus to Filtrate-PTM – the effect of different scales. Water Research 40(6): 1143-1154. https://doi.org/10.1016/j.watres.2006.01.009
[2] Bellier, N., F. Chazarenc, and Y. Comeau (2006) Phosphorus removal from wastewater by mineral apatite. Water Research 40(15): 2965-2971. https://doi.org/10.1016/j.watres.2006.05.016
[3] Dodds, Walter K., Wes W. Bouska, Jefferey L. Eitzmann, Tyler J. Pilger, Kristen L. Pitts, Alyssa J. Riley, Joshua T. Schloesser, and Darren J. Thornbrugh (2009) Eutrophication of U. S. Freshwaters: analysis of potential economic damages. Environmental Science & Technology 43(1): 12-19. https://doi.org/10.1021/es801217q
[4] Drenkova-Tuhtan, Asya, Karl Mandel, Anja Paulus, Carsten Meyer, Frank Hutler, Carsten Gellermann, Gerhard Sextl, Matthias Franzreb, and Heidrun Steinmetz (2013) Phosphate recovery from wastewater using engineered superparamagnetic particles modified with layered double hydroxide ion exchangers. Water Research 47(15): 5670-5677. https://doi.org/10.1016/j.watres.2013.06.039
[5] Galil, N., K. Malachi, C. Sheindorf (2009) Biological nutrient removal in membrane biological reactors. Environmental Engineering Science 26(4):817-824. https://doi.org/10.1089/ees.2008.0234
[6] Hutnik, N., A. Kozik, A. Mazienczuk, K. Piotrowski, B. Wierzbowska, and A. Matynia (2013) Phosphates (V) recovery from phosphorus mineral fertilizers industry wastewater by continuous struvite reaction crystallization process. Water Research 47(11): 3635-3643. https://doi.org/10.1016/j.watres.2013.04.026
[7] Ji, G., Y. Zhou, J. Tong (2010) Nitrogen and phosphorous adsorption behavior of ceramsite material made from coal ash and metallic iron. Environmental Engineering Science 27(10):871-878. https://doi.org/10.1089/ees.2010.0086
[8] Kuzawa, K., Y. J. Jung, Y. Kiso, T. Yamada, M. Nagai, and T. G. Lee (2006) Phosphate removal and recovery with a synthetic hydrotalcite as an adsorbent. Chemosphere 62(1): 45-52. https://doi.org/10.1016/j.chemosphere.2005.04.015
[9] Lamers, Leon P. M., Sarah-J. Falla, Edyta M. Samborska, Ivo A. R. van Dulken, Gijs van Hengstum and Jan G. M. Roelofs (2006) Factors controlling the extent of eutrophication and toxicity in sulfate-polluted freshwater wetlands. Limnology and Oceanography 47(2): 585-593. https://doi.org/10.4319/lo.2002.47.2.0585
[10] Li, H., H. Zhao, H. Hao, J. Liang, F. Zhao, L. Xiang, X. Yang, Z. He, and P. Stoffela (2011) Enhancement of nutrient removal from eutrophic water by a plant-microorganisms combined system. Environmental Engineering Science 28(8):543-554. https://doi.org/10.1089/ees.2011.0026
[11] Mandel, Karl, Asya Drenkova-Tuhtan, Frank Hutter, Carsten Gellermann, Heidrun Steinmetz, and Gerhard Sextl (2013) Layered double hydroxide ion exchangers on superparamagnetic microparticles for recovery of phosphate from waste water. Journal of Materials Chemistry A 1(5): 1840-1848. https://doi.org/10.1039/C2TA00571A
[12] Mielczarek, A., H. Nguyen, J. Niellsen, and P. Nielsen (2013) Population dynamics of bacteria involved in enhanced biological phosphorus removal in Danish wastewater treatment plants. Water Research 47(4): 1529-1544. https://doi.org/10.1016/j.watres.2012.12.003
[13] Norwack, B. and A. T. Stone (2006) Competitive adsorption of phosphate and phosphonates onto goethite. Water Research 40(11): 2201– 2209. https://doi.org/10.1016/j.watres.2006.03.018
[14] Novotny, Vladimir (2011) The danger of hypertrophic status of water supply impoundments resulting from excessive nutrient loads from agricultural and other sources. Journal of Water Sustainability 1(1): 1-22.
[15] Pitakteerathem, N., A. Hafuka, H. Satoh, and Y. Watanabe (2013) High-efficiency removal of phosphate from water by zirconium sulfate-surfactant micelle mesostructure immobilized on polymer matrix. Water Research 47(11): 3583-3590. https://doi.org/10.1016/j.watres.2013.04.006
[16] Schabenberger, O., Pierce, F.J. (2002) Contemporary Statistical Models for the Plant and Soil Sciences. CRC Press, 343.
[17] Schindler, D. W. (1977) Evolution of phosphorus limitation in lakes: Natural mechanisms compensate for deficiencies of nitrogen and carbon in eutrophied lakes. Science 195: 260-262. https://doi.org/10.1126/science.195.4275.260
[18] Schindler, D. W. (2006) Recent advances in the understanding and management of eutrophication. Limnology and Oceanography 51(1, part 2): 356-363. https://doi.org/10.4319/lo.2006.51.1_part_2.0356
[19] Smolders, A. J. P., L. P. M. Lamers, E. C. H. E. T. Lucassen, G. Ven Der Velde, and J. G. M. Roelofs (2006) Internal Eutrophication: How it works and what to do about it – a review. Chemistry and Ecology 22(2): 93-111. https://doi.org/10.1080/02757540600579730
[20] Terry, Patricia A. (2009) Removal of nitrates and phosphates by ion exchange with hydrotalcite. Environmental Engineering Science 26(3): 691-696. https://doi.org/10.1089/ees.2007.0222
[21] United States Environmental Protection Agency (1986) Quality criteria for water 1986. EPA 440/5-86-001. Online available at http://water.epa.gov/scitech/swguidance/standards/criteria/aqlife/upload/2009_01_13_criteria_goldbook.pdf
[22] United States Environmental Protection Agency (1999) Health Effects from Exposure to High Levels of Sulphatein Drinking Water Study. EPA 815-R-99-001. Online available at: http://www.epa.gov/ogwdw/contaminants/unregulated/pdfs/study_sulfate_epa-cdc.pdf.
[23] U. S. Senate Subcommittee on Water and Wildlife. Testimony of Andy Buchsbaum Regional Executive Director, Great Lakes Natural Resources Center National Wildlife Federation (October 4, 2011) Nutrient pollution: An overview of nutrient reduction approaches. Retrieved from: http://epw.senate.gov/public/index.cfm?FuseAction=Files.View & FileStore_id=8d780b54-8647-4f33-b91b-6d15dfb2412e.
[24] Yin, H., M. Kong, and C. Fan (2013) Batch investigations on P immobilization from wastewaters and sediment using natural calcium rich sepiolote as a reactive material. Water Research 47(13): 4247-4258. https://doi.org/10.1016/j.watres.2013.04.044
[25] Zhang, M., B. Gao, Y. Yao, and M. Inyang (2013) Phosphate removal ability of biochar/MgAl-LDH ultra-fine composites prepared by liquid-phase deposition. Chemophere 92(8): 1042-1047. https://doi.org/10.1016/j.chemosphere.2013.02.050
[26] Zhu, Li, Cesar B. Granda, and Mark T. Holtzapple (2011) Prevention of calcium sulphateformation in seawater desalination by ion exchange. Desalination and Water Treatment 36:57-64. https://doi.org/10.5004/dwt.2011.1862

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