Characterization of Nanomaterials: X-ray Diffraction Method, Electron Microscopy and Light Scattering

$20.00

Characterization of Nanomaterials: X-ray Diffraction Method, Electron Microscopy and Light Scattering

Bichitra Nandi Ganguly

This chapter reviews methods to illuminate the molecular architecture of nanoparticles through special high resolution techniques such as X-ray diffraction studies (XRD), which is used to examine the crystallinity of a sample, the powder diffraction method which assesses the size of the nano crystalline sample by Debye-Scherrer method. Transmission (TEM) and scanning electron microscopic (SEM) methods are used to get information on the structural morphology, elemental composition and size of the nanoparticles. Further, the dynamic light scattering (DLS) method gives an illustration of measurement of hydrodynamic radii of nanoparticles in its dispersed phase. These are some of the basic tools one needs to use for the physical characterization of nanoparticles. Some examples are also given in order to better understand the processes.

Keywords
X-Ray Diffraction, Debye Scherrer Method, Electron Microscopy, Light Scattering

Published online 7/1/2018, 19 pages

DOI: http://dx.doi.org/10.21741/9781945291739-5

Part of the book on Nanomaterials in Bio-Medical Applications

References
[1] B.D. Cullity, S.R. Stock: Elements of X-ray Diffraction, Prentice-Hall, Englewood Cliffs, New Jersey, 2001.
[2] T.E.M. Staab, R. Krause-Rehberg, B. Kieback: Review Positron annihilation in fine-grained materials and fine powders—an application to the sintering of metal powders, J Mater Sci 34 (1999) 3833-3851. https://doi.org/10.1023/A:1004666003732
[3] T. Ungár, G. Tichy, J. Gubicza, et al., Correlation between subgrains and coherently scattering domains., Powder Diffr 20 (2005) 366-375. https://doi.org/10.1154/1.2135313
[4] GK Williamson, WH Hall: X-ray line broadening from field aluminium and Wolfram., Acta Metall 1(1953) 22-31. https://doi.org/10.1016/0001-6160(53)90006-6

[5] Sreetama Dutta and Bichitra N. Ganguly, Characterization of ZnO nanoparticles grown in presence of Folic acid template, J. Nanobiotechnology 10 (2012) 29-38. https://doi.org/10.1186/1477-3155-10-29
[6] R. Erni, M.D. Rossell, C. Kisielowski, U. Dahmen, Atomic-Resolution Imaging with a Sub-50-pm Electron Probe. Physical Review Letters. 102 (2009) 096101. https://doi.org/10.1103/PhysRevLett.102.096101
[7] Bichitra Nandi Ganguly, Vivek Verma, Debanuj Chatterjee, Biswarup Satpati, Sushanta Debnath and Partha Saha, Study of Gallium Oxide Nanoparticles Conjugated with -cyclodextrin -An Application to Combat Cancer, ACS Materials and Interfaces 8 (2016) 17127- 17137. https://doi.org/10.1021/acsami.6b04807
[8] Bichitra Nandi Ganguly , Buddhadeb Maity, Tapan Kumar Maity, Joydeb Manna, Modhusudan Roy, Manabendra Mukherjee , Sushanta Debnath, Partha Saha, Nagaraju Shilpa, and Rohit Kumar Rana, l-Cysteine-Conjugated Ruthenium Hydrous Oxide Nanomaterials with Anticancer Active Application, Langmuir 4 (2018) 1447-1456. https://doi.org/10.1021/acs.langmuir.7b01408
[9] Sreetama Dutta and Bichitra Nandi Ganguly, Characteristics of Dispersed ZnO-Folic acid Conjugate in Aqueous Medium, Advances in Nanoparticles 3(2014) 23-30. https://doi.org/10.4236/anp.2014.31004