Removal of heavy metals using graphene composites

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Removal of heavy metals using graphene composites

Mukesh Kumar, Prashant Singh, Manish Kumar Gautam

The presence of heavy metal ions in water is a serious risk to the human health and other living forms on earth because the indiscriminate disposal of these non-biodegradable pollutants worldwide. Nanotechnology-based developed current nano-adsorbent are the demand of the current research for the effective removal of highly toxic heavy metal ions from the wastewaters. Graphene and graphene oxide based nano-adsorbent play a major role in the effective removal of heavy metal ions because the unique nature of graphene such as extremely high electronic mobility, large surface area to volume ratio, weight, and preponderance of exposed edge planes to enhance charge storage which are responsible for their higher absorption capacity when compared with other materials. Hence, the applicability of graphene and its composites as an adsorbent for the removal of heavy metal ions is summarized in this chapter.

Keywords
Graphene, Graphene Oxide, Nanoadsorbent, Surface Adsorption, Heavy Metal Ions, Grafting, Magnetite, Functionalization

Published online 8/1/2017, 37 pages

DOI: http://dx.doi.org/10.21741/9781945291357-6

Part of Inorganic Pollutants in Wastewater

References
[1] G. Zhao, J. Li, X. Ren, C. Chen, X. Wang, Few-layered graphene oxide nanosheets as superior sorbents for heavy metal ion pollution management, Environ. Sci. Technol., 45(2011) 10454-10462. https://doi.org/10.1021/es203439v
[2] G. Gollavelli, C.-C. Chang, Y.-C. Ling, Facile synthesis of smart magnetic graphene for safe drinking water: heavy metal removal and disinfection control, ACS Sust. Chem. & Eng., 1(2013) 462-472. https://doi.org/10.1021/sc300112z
[3] X. Wang, Y. Guo, L. Yang, M. Han, J. Zhao, X. Cheng, Nanomaterials as sorbents to remove heavy metal ions in wastewater treatment, Environ. & Anal. Toxicol., 2(2012) 1-5. https://doi.org/10.4172/2161-0525.1000154
[4] C. Chen, X. Wang, Adsorption of Ni(II) from Aqueous solution using oxidized multiwall carbon nanotubes, Ind. Eng. Chem. Res., 45(2006) 9144-9149. https://doi.org/10.1021/ie060791z
[5] Y. Y. Liang, D. Q. Wu, X. L. Feng, K. M€ullen, Dispersion of graphene sheets in organic solvent supported by ionic interactions, Adv. Mater., 21(2009) 1679-1683. https://doi.org/10.1002/adma.200803160
[6] X. Li, X. Wang, L. Zhang, S. Lee, H. Dai, Chemically derived, ultrasmooth graphene nanoribbon semiconductors, Science, 319(2008) 1229-1232. https://doi.org/10.1126/science.1150878
[7] T. Mueller, F. N. Xia, P. Avouris, Graphene photodetectors for high-speed optical communications, Nat. Photonics, 4(2010) 297−301. https://doi.org/10.1038/nphoton.2010.40
[8] L. Zhang, J. Xia, Q. Zhao, L. Liu, Z. Zhang, Functional graphene oxide as a nanocarrier for controlled loading and targeted delivery of mixed anticancer drugs, Small, 6(2010) 537−544. https://doi.org/10.1002/smll.200901680
[9] K. C. Kemp, H. Seema, M. Saleh, N. H. Le, K. Mahesh, V. Chandra, K. S. Kim, Environmental applications using graphene composites: Water remediation and gas adsorption, Nanoscale, 5(2013) 3149−3171. https://doi.org/10.1039/c3nr33708a
[10] G. Zhao, J. Li, X. Ren, C. Chen, X. Wang, Few-layered graphene oxide nanosheets as superior sorbents for heavy metal ion pollution management, Environ. Sci. Technol., 45(2011) 10454−10462. https://doi.org/10.1021/es203439v
[11] R. R. Nair, H. A. Wu, P. N. Jayaram, I. V. Grigorieva, A. K. Geim, Unimpeded permeation of water through helium-leak-tight graphene-based membranes, Science, 335(2012) 442−444. https://doi.org/10.1126/science.1211694
[12] Y. Yoon, W. K. Park, T.-M. Hwang, D. H. Yoon, W. S. Yang, J.-W. Kang, Comparative evaluation of magnetite–graphene oxide and magnetite-reduced graphene oxide composite for As(III) and As(V) removal, J. Hazard. Mater., 304(2016) 196-204. https://doi.org/10.1016/j.jhazmat.2015.10.053
[13] C. J. Madadrang, H. Y. Kim, G. Gao, N. Wang, J. Zhu, H. Feng, M. Gorring, M. L. Kasner, S. Hou, Adsorption Behavior of EDTA-Graphene Oxide for Pb(II) Removal, ACS Appl. Mater. & Interf., 4(2012) 1186-1193. https://doi.org/10.1021/am201645g
[14] L. Fan, C. Luo, M. Sun, X. Li, H. Qiu, Highly selective adsorption of lead ions by water-dispersible magnetic chitosan/graphene oxide composites, Coll. and Surfac. B: Biointerf., 103(2013) 523-529. https://doi.org/10.1016/j.colsurfb.2012.11.006
[15] S. Luo, X. Xu, G. Zhou, C. Liu, Y. Tang, Y. Liu, Amino siloxane oligomer-linked graphene oxide as an efficient adsorbent for removal of Pb(II) from wastewater, J. Hazard. Mater., 274(2014) 145-155. https://doi.org/10.1016/j.jhazmat.2014.03.062
[16] Z. Xu, Y. Zhang, X. Qian, J. Shi, L. Chen, B. Li, J. Niu, L. Liu, One step synthesis of polyacrylamide functionalized graphene and its application in Pb(II) removal, Appl. Surf. Sci., 316(2014) 308-314. https://doi.org/10.1016/j.apsusc.2014.07.155
[17] S. Wan, F. He, J. Wu, W. Wan, Y. Gu, B. Gao, Rapid and highly selective removal of lead from water using graphene oxide-hydrated manganese oxide nanocomposites, J. Hazard. Mater., 314(2016) 32-40. https://doi.org/10.1016/j.jhazmat.2016.04.014
[18] J.-H. Deng, X.-R. Zhang, G.-M. Zeng, J.-L. Gong, Q.-Y. Niu, J. Liang, Simultaneous removal of Cd(II) and ionic dyes from aqueous solution using magnetic graphene oxide nanocomposite as an adsorbent, Chem. Eng. J., 226(2013) 189-200. https://doi.org/10.1016/j.cej.2013.04.045
[19] J. Liu, H. Du, S. Yuan, W. He, Z. Liu, Synthesis of thiol-functionalized magnetic graphene as adsorbent for Cd(II) removal from aqueous systems, J. Environ. Chem. Eng., 3(2015) 617-621. https://doi.org/10.1016/j.jece.2015.01.016
[20] H. He, C. Gao, Supraparamagnetic, conductive, and processable multifunctional graphene nanosheets coated with high-density Fe3O4 nanoparticles ACS Appl. Mater. Interfaces, 2(2010) 3201-3210. https://doi.org/10.1021/am100673g
[21] Y. Wang, S. Liang, B. Chen, F. Guo, S. Yu, Y. Tang, Synergistic removal of pb(ii), cd(ii) and humic acid by fe3o4@mesoporous silica-graphene oxide composites, PLOS One, 8(2013) e65634. https://doi.org/10.1371/journal.pone.0065634
[22] S. Thakur, G. Das, P. K. Raul, N. Karak, Green one-step approach to prepare sulfur/reduced graphene oxide nanohybrid for effective mercury ions removal, J. Phys. Chem. C, 117(2013) 7636-7642. https://doi.org/10.1021/jp400221k
[23] S. Kabiri, D. N. H. Tran, S. Azari, D. Losic, Graphene-diatom silica aerogels for efficient removal of mercury ions from water, ACS Appl. Mat. & Interf., 7(2015) 11815-11823. https://doi.org/10.1021/acsami.5b01159
[24] S. A. Katz, H. Salem, The Biological and environmental chemistry of chromium, VCH, New York, . (1994)
[25] K. Z. Setshedi, M. Bhaumik, M. S. Onyango, A. Maity, High-performance towards Cr(VI) removal using multi-active sites of polypyrrole–graphene oxide nanocomposites: Batch and column studies, Chem. Eng. J., 262(2015) 921-931. https://doi.org/10.1016/j.cej.2014.10.034
[26] X. Zhang, R. Bai, Surface electric properties of polypyrrole in aqueous solutions, Langmuir, 19(2003) 10703-10709. https://doi.org/10.1021/la034893v
[27] R. Dubey, J. Bajpai, A. K. Bajpai, Green synthesis of graphene sand composite (GSC) as novel adsorbent for efficient removal of Cr (VI) ions from aqueous solution, J. Wat. Proc. Eng., 5(2015) 83-94. https://doi.org/10.1016/j.jwpe.2015.01.004
[28] J. Zhu, S. Wei, H. Gu, B. Rapole, Q. Wang, Z. Luo, N. Haloolaarachchige, D. P. Young, Z. Guo, One-pot synthesis of magnetic graphene nanocomposites decorated with core@double-shell nanoparticles for fast chromium removal, Environ. Sci. Technol. , 46(2012) 977-985. https://doi.org/10.1021/es2014133
[29] D. Dinda, S. Kumar Saha, Sulfuric acid doped poly diaminopyridine/graphene composite to remove high concentration of toxic Cr(VI), J. Hazard. Mater., 291(2015) 93-101. https://doi.org/10.1016/j.jhazmat.2015.02.065
[30] J. F. Ferguson, J. Gavis, A review of the arsenic cycle in natural waters, Water Res., 6(1972) 1259-1274. https://doi.org/10.1016/0043-1354(72)90052-8
[31] V. Chandra, J. Park, Y. Chun, J. W. Lee, I.-C. Hwang, K. S. Kim, Water-dispersible magnetite-reduced graphene oxide composites for arsenic removal, ACS Nano, 4(2010) 3979-3986. https://doi.org/10.1021/nn1008897
[32] Q. Zhang, B. Pan, W. Zhang, B. Pan, Q. Zhang, H. Ren, Arsenate removal from aqueous media by nanosized hydrated ferric oxide (HFO)-loaded polymeric sorbents: Effect of HFO loadings, Ind. Eng. Chem. Res., 47(2008) 3957-396. https://doi.org/10.1021/ie800275k
[33] T.-F. Lin, J.-K. Wu, Adsorption of arsenite and arsenate within activated alumina grains: Equilibrium and Kinetics, Water Res., 35(2001) 2049-2057. https://doi.org/10.1016/S0043-1354(00)00467-X