Kinetics study of nutrients removal from synthetic wastewater using media as submerged in continuous activated sludge system

Kinetics study of nutrients removal from synthetic wastewater using media as submerged in continuous activated sludge system

BAKER NASSER Saleh Al-dhawi, SHAMSUL RAHMAN Mohamed Kutty, LAVANİA Baloo, AHMED HUSAİNİ Jagaba, AIBAN ABDULHAKIM Saeed Ghaleb, NAJİB MOHAMMED Yahya Almahbashi, VİCKY Kumar, AZMATULLAH Noor, ANWAR AMEEN Hezam Saeed, AL-BARAA Abdulrahman Al-Mekhlafi, YASER ABDULWAHAB Ali Alsaeedi

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Abstract. Domestic wastewater effluents are one of the main sources of environmental contaminants such as nutrients. Wastewater has been treated with biological processes for over a century to remove contaminants. Conventional wastewater treatment plants continue to struggle to meet Malaysian discharge limits. Stringent regulation enforced by governing authorities makes it obligatory to comply with discharge guidelines to fulfill ammonia and nitrate levels. To assist the system in meeting these limits, it is recommended that a submerged attached growth Palm Oil Clinker (POC) can be incorporated into the conventional treatment system. The study was conducted in a continuous submerged attach growth conventional activated sludge which was evaluated for the treatment of wastewater (CSAR). A basket was installed in the aeration tank of the reactor to submerge (POC). Two identical reactors were operated for each reactor of study which (A) was referred to as submerged media reactor while (B) was referred to as control. The studies were carried out at various influent flow rates between 5 and 30 L/d, and constant organic load rate OLR. Parameters such as NH4-N, and NO3-N, were monitored. Generally, Ammonia and Nitrate were highly removed. At all conditions of flow rate (5-30 L/d), the maximum and minimum NH4-N removal is 92% and 85%. The experimental data were validated through well-established mathematical bio-kinetic models such as the First order model, and Monod models. The kinetic coefficients R2 of the first-order model of the substrate removal rate were 0.97 for Ammonia. The steady-state data was fitted to both models obtained at various flowrate. Monod’s kinetic model was appropriate for describing experimental results in terms of microbial growth parameters. The kinetic coefficients R2 (0.984) and Ks 303 for the removal of Ammonia, respectively. While µmax 10 g/L.d for Ammonia removal respectively.

Keywords
Kinetic, Nutrients, Synthetic wastewater, Palm Oil Clinker, Submerged, Continuous Flow

Published online 5/20/2023, 11 pages
Copyright © 2023 by the author(s)
Published under license by Materials Research Forum LLC., Millersville PA, USA

Citation: BAKER NASSER Saleh Al-dhawi, SHAMSUL RAHMAN Mohamed Kutty, LAVANİA Baloo, AHMED HUSAİNİ Jagaba, AIBAN ABDULHAKIM Saeed Ghaleb, NAJİB MOHAMMED Yahya Almahbashi, VİCKY Kumar, AZMATULLAH Noor, ANWAR AMEEN Hezam Saeed, AL-BARAA Abdulrahman Al-Mekhlafi, YASER ABDULWAHAB Ali Alsaeedi, Kinetics study of nutrients removal from synthetic wastewater using media as submerged in continuous activated sludge system, Materials Research Proceedings, Vol. 29, pp 87-97, 2023

DOI: https://doi.org/10.21741/9781644902516-12

The article was published as article 12 of the book Sustainable Processes and Clean Energy Transition

Content from this work may be used under the terms of the Creative Commons Attribution 3.0 license. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.

References
[1] I. Naz, S. Seher, I. Perveen, D. P. Saroj, and S. Ahmed, “Physiological activities associated with biofilm growth in attached and suspended growth bioreactors under aerobic and anaerobic conditions,” Environ Technol, vol. 36, no. 13-16, pp. 1657-71, Jul-Aug 2015. https://doi.org/10.1080/09593330.2014.1003614
[2] L. Machineni, “Review on biological wastewater treatment and resources recovery: attached and suspended growth systems,” Water Science and Technology, vol. 80, no. 11, pp. 2013-2026, 2019. https://doi.org/10.2166/wst.2020.034
[3] A. A. H. Saeed et al., “Pristine and magnetic kenaf fiber biochar for Cd2+ adsorption from aqueous solution,” International journal of environmental research and public health, vol. 18, no. 15, p. 7949, 2021. https://doi.org/10.3390/ijerph18157949
[4] F. Sher et al., “Removal of micropollutants from municipal wastewater using different types of activated carbons,” Journal of Environmental Management, vol. 278, p. 111302, 2021. https://doi.org/10.1016/j.jenvman.2020.111302
[5] A. Jagaba et al., “Derived hybrid biosorbent for zinc (II) removal from aqueous solution by continuous-flow activated sludge system,” Journal of Water Process Engineering, vol. 34, p. 101152, 2020. https://doi.org/10.1016/j.jwpe.2020.101152
[6] B. N. S. Al-dhawi et al., “Treatment of synthetic wastewater by using submerged attached growth media in continuous activated sludge reactor system,” 2022.
[7] J. N. Edokpayi, J. O. Odiyo, and O. S. Durowoju, “Impact of wastewater on surface water quality in developing countries: a case study of South Africa,” Water quality, vol. 10, p. 66561, 2017. https://doi.org/10.5772/66561
[8] N. K. Singh and A. A. Kazmi, “Environmental performance and microbial investigation of a single stage aerobic integrated fixed-film activated sludge (IFAS) reactor treating municipal wastewater,” Journal of environmental chemical engineering, vol. 4, no. 2, pp. 2225-2237, 2016. https://doi.org/10.1016/j.jece.2016.04.001
[9] N. K. Singh, A. A. Kazmi, and M. Starkl, “Treatment performance and microbial diversity under dissolved oxygen stress conditions: Insights from a single stage IFAS reactor treating municipal wastewater,” Journal of the Taiwan Institute of Chemical Engineers, vol. 65, pp. 197-203, 2016. https://doi.org/10.1016/j.jtice.2016.05.002
[10] M. Ali, N. K. Singh, A. Bhatia, S. Singh, A. Khursheed, and A. A. Kazmi, “Sulfide production control in UASB reactor by addition of iron salt,” Journal of Environmental Engineering, vol. 141, no. 6, p. 06014008, 2015. https://doi.org/10.1061/(ASCE)EE.1943-7870.0000911
[11] R. K. Sinha, S. Herat, G. Bharambe, and A. Brahambhatt, “Vermistabilization of sewage sludge (biosolids) by earthworms: converting a potential biohazard destined for landfill disposal into a pathogen-free, nutritive and safe biofertilizer for farms,” Waste Management & Research, vol. 28, no. 10, pp. 872-881, 2010. https://doi.org/10.1177/0734242X09342147
[12] G. Tchobanoglous et al., “Waterwater Engineering: Treatment and Resource Recovery, Metcalf and Eddy Inc,” ed: McGraw-Hill, New York, 2014.
[13] A. A. Hezam Saeed, N. Y. Harun, S. Sufian, and M. F. Bin Aznan, “Effect of adsorption parameter on the removal of nickel (II) by low-cost adsorbent extracted from corn cob,” International Journal of Advanced Research in Engineering and Technology (IJARET), vol. 11, no. 9, 2020.
[14] S. Pal, U. Sarkar, and D. Dasgupta, “Dynamic simulation of secondary treatment processes using trickling filters in a sewage treatment works in Howrah, west Bengal, India,” Desalination, vol. 253, no. 1-3, pp. 135-140, 2010. https://doi.org/10.1016/j.desal.2009.11.019
[15] J. Bassin, I. Dias, S. Cao, E. Senra, Y. Laranjeira, and M. Dezotti, “Effect of increasing organic loading rates on the performance of moving-bed biofilm reactors filled with different support media: Assessing the activity of suspended and attached biomass fractions,” Process Safety and Environmental Protection, vol. 100, pp. 131-141, 2016. https://doi.org/10.1016/j.psep.2016.01.007
[16] S. Pandit, S. Sarode, and K. Chandrasekhar, “Fundamentals of bacterial biofilm: Present state of art,” in Quorum Sensing and its Biotechnological Applications: Springer, 2018, pp. 43-60. https://doi.org/10.1007/978-981-13-0848-2_3
[17] A. A. H. Saeed et al., “Moisture content impact on properties of briquette produced from rice husk waste,” Sustainability, vol. 13, no. 6, p. 3069, 2021. https://doi.org/10.3390/su13063069
[18] J. A. Glaser, “Biological degradation of polymers in the environment,” in Plastics in the Environment: IntechOpen, 2019. https://doi.org/10.5772/intechopen.85124
[19] A. A. H. Saeed, N. Y. Harun, and N. Zulfani, “Heavy metals capture from water sludge by kenaf fibre activated carbon in batch adsorption,” Journal of Ecological Engineering, vol. 21, no. 6, 2020. https://doi.org/10.12911/22998993/123249
[20] H. J. Busscher, W. Norde, P. K. Sharma, and H. C. Van der Mei, “Interfacial re-arrangement in initial microbial adhesion to surfaces,” Current Opinion in Colloid & Interface Science, vol. 15, no. 6, pp. 510-517, 2010. https://doi.org/10.1016/j.cocis.2010.05.014
[21] K. Biswas and S. J. Turner, “Microbial community composition and dynamics of moving bed biofilm reactor systems treating municipal sewage,” Applied and environmental microbiology, vol. 78, no. 3, pp. 855-864, 2012. https://doi.org/10.1128/AEM.06570-11
[22] N. Y. Harun, A. A. H. Saeed, A. Vegnesh, and L. A. Ramachandran, “Abundant nipa palm waste as Bio-pellet fuel,” Materials Today: Proceedings, vol. 42, pp. 436-443, 2021. https://doi.org/10.1016/j.matpr.2020.10.169
[23] S. Tabassum, Y. Zhang, and Z. Zhang, “An integrated method for palm oil mill effluent (POME) treatment for achieving zero liquid discharge-a pilot study,” Journal of Cleaner Production, vol. 95, pp. 148-155, 2015. https://doi.org/10.1016/j.jclepro.2015.02.056
[24] B. Al-dhawi, S. R. Kutty, N. Almahbashi, A. Noor, and A. H. Jagaba, “Organics removal from domestic wastewater utilizing palm oil clinker (POC) media in a submerged attached growth systems,” International Journal of Civil Engineering and Technology, vol. 11, no. 6, pp. 1-7, 2020. https://doi.org/10.34218/IJCIET.11.6.2020.001
[25] B.-T. Dang et al., “Non-submerged attached growth process for domestic wastewater treatment: Influence of media types and internal recirculation ratios,” Bioresource Technology, vol. 343, p. 126125, 2022. https://doi.org/10.1016/j.biortech.2021.126125
[26] N. Y. Harun, T. J. Han, T. Vijayakumar, A. Saeed, and M. T. Afzal, “Ash deposition characteristics of industrial biomass waste and agricultural residues,” Materials Today: Proceedings, vol. 19, pp. 1712-1721, 2019. https://doi.org/10.1016/j.matpr.2019.11.201
[27] J. Kanadasan and H. Abdul Razak, “Utilization of palm oil clinker as cement replacement material,” Materials, vol. 8, no. 12, pp. 8817-8838, 2015. https://doi.org/10.3390/ma8125494
[28] A. H. Jagaba et al., Palm oil clinker as a waste by-product: Utilization and circular economy potential. IntechOpen London, 2021.
[29] A. P. H. Association, A. W. W. Association, W. P. C. Federation, and W. E. Federation, Standard methods for the examination of water and wastewater. American Public Health Association., 1915.
[30] M. Z. Jumaat, U. J. Alengaram, R. Ahmmad, S. Bahri, and A. S. Islam, “Characteristics of palm oil clinker as replacement for oil palm shell in lightweight concrete subjected to elevated temperature,” Construction and Building Materials, vol. 101, pp. 942-951, 2015. https://doi.org/10.1016/j.conbuildmat.2015.10.104
[31] J. Kanadasan, A. F. A. Fauzi, H. A. Razak, P. Selliah, V. Subramaniam, and S. Yusoff, “Feasibility studies of palm oil mill waste aggregates for the construction industry,” Materials, vol. 8, no. 9, pp. 6508-6530, 2015. https://doi.org/10.3390/ma8095319
[32] S. A. Kabir, U. J. Alengaram, M. Z. Jumaat, S. Yusoff, A. Sharmin, and I. I. Bashar, “Performance evaluation and some durability characteristics of environmental friendly palm oil clinker based geopolymer concrete,” Journal of cleaner production, vol. 161, pp. 477-492, 2017. https://doi.org/10.1016/j.jclepro.2017.05.002
[33] F. L. Burton and G. Tchobanoglous, Wastewater Engineering: treatment, disposal, and reuse. McGraw-Hill, 2018.
[34] C. W. Teo and P. C. Y. Wong, “Enzyme augmentation of an anaerobic membrane bioreactor treating sewage containing organic particulates,” Water research, vol. 48, pp. 335-344, 2014. https://doi.org/10.1016/j.watres.2013.09.041
[35] K. Gajanan, “Nutrients Requirements in Biological Industrial Waste Water Treatment,” 2015.
[36] J. T. Novak, S. Banjade, and S. N. Murthy, “Combined anaerobic and aerobic digestion for increased solids reduction and nitrogen removal,” Water research, vol. 45, no. 2, pp. 618-624, 2011. https://doi.org/10.1016/j.watres.2010.08.014
[37] E. W. Rice, R. B. Baird, A. D. Eaton, and L. S. Clesceri, Standard methods for the examination of water and wastewater. American public health association Washington, DC, 2012.
[38] D. Manu and A. K. Thalla, “Artificial intelligence models for predicting the performance of biological wastewater treatment plant in the removal of Kjeldahl Nitrogen from wastewater,” Applied Water Science, vol. 7, no. 7, pp. 3783-3791, 2017. https://doi.org/10.1007/s13201-017-0526-4
[39] L. Metcalf, H. P. Eddy, and G. Tchobanoglous, Wastewater engineering: treatment, disposal, and reuse. McGraw-Hill New York, 1979.
[40] M. E. Argun, S. Dursun, C. Ozdemir, and M. Karatas, “Heavy metal adsorption by modified oak sawdust: Thermodynamics and kinetics,” Journal of hazardous materials, vol. 141, no. 1, pp. 77-85, 2007. https://doi.org/10.1016/j.jhazmat.2006.06.095
[41] M. M. Amin, M. H. Khiadani, A. Fatehizadeh, and E. Taheri, “Validation of linear and non-linear kinetic modeling of saline wastewater treatment by sequencing batch reactor with adapted and non-adapted consortiums,” Desalination, vol. 344, pp. 228-235, 2014. https://doi.org/10.1016/j.desal.2014.03.032
[42] P. Mullai and M. Yogeswari, “Substrate removal kinetics of hydrogen production in an anaerobic sludge blanket filter,” Separation Science and Technology, vol. 50, no. 7, pp. 1093-1100, 2015. https://doi.org/10.1080/01496395.2014.969806
[43] R. Bhattacharya and D. Mazumder, “Evaluation of nitrification kinetics for treating ammonium nitrogen enriched wastewater in moving bed hybrid bioreactor,” Journal of Environmental Chemical Engineering, vol. 9, no. 1, p. 104589, 2021. https://doi.org/10.1016/j.jece.2020.104589
[44] Y. J. Chan, M. F. Chong, and C. L. Law, “Performance and kinetic evaluation of an integrated anaerobic-aerobic bioreactor in the treatment of palm oil mill effluent,” Environmental technology, vol. 38, no. 8, pp. 1005-1021, 2017. https://doi.org/10.1080/09593330.2016.1217053
[45] H. A. Hasan, S. R. S. Abdullah, S. K. Kamarudin, N. T. Kofli, and N. Anuar, “Kinetic evaluation of simultaneous COD, ammonia and manganese removal from drinking water using a biological aerated filter system,” Separation and Purification Technology, vol. 130, pp. 56-64, 2014. https://doi.org/10.1016/j.seppur.2014.04.016
[46] S. Katoh, F. Yoshida, and J.-i. Horiuchi, Biochemical engineering. Wiley Online Library, 2015. https://doi.org/10.1002/9783527684984