Ion Exchange Resins for Selective Separation of Toxic Metals


Ion Exchange Resins for Selective Separation of Toxic Metals

Arun Kumar Pramanik, Nirmala Tamang, Abhik Chatterjee, Ajaya Bhattarai, Bidyut Saha

The proper resin selection can make ion exchange a cost-effective and effective pollution control method. Toxic ions in drinking water can be exchanged for other ions via solid ion exchange resin. Nowadays metals are common contaminants in surface water, groundwater, industrial wastewater and other effluent from various sources in the world. Such metals openly challenge and seriously threaten the environment and all living beings. In present time, huge techniques and instruments are developed to separate and filter the metals coming from different sources.

Ion Exchange Resin, Toxic Metal, Effective Pollution Control Method

Published online 12/20/2022, 20 pages

Citation: Arun Kumar Pramanik, Nirmala Tamang, Abhik Chatterjee, Ajaya Bhattarai, Bidyut Saha, Ion Exchange Resins for Selective Separation of Toxic Metals, Materials Research Foundations, Vol. 137, pp 55-74, 2023


Part of the book on Ion Exchange Resins

[1] J. Briffa, E. Sinagra, R. Blundell, Heavy metal pollution in the environment and their toxicological effects on humans, Heliyon. 6 (2020) e04691.
[2] M. Balali-Mood, K. Naseri, Z. Tahergorabi, M.R. Khazdair, M. Sadeghi, Toxic Mechanisms of Five Heavy Metals: Mercury, Lead, Chromium, Cadmium, and Arsenic. Front. Pharmacol. 12 (2021) 643972.
[3] ScienceDirect, Ion exchange. (accessed 25 March 2022)
[4] Wikipedia, Ion exchange resin, (accessed 25 March 2022)
[5] F. Dardel, T.V. Arden, “Ion Exchangers” in Ullmann’s Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim. 2008).
[6] Matten Plant, Types of Resins. (accessed 25 March 2022)
[7] H.A. Ezzeldin, A. Apblett, G.L. Foutch, Synthesis and Properties of Anion Exchangers Derived from Chloromethyl Styrene Codivinylbenzene and Their Use in Water Treatment, International Journal of Polymer Science. 684051 (2010) 9.
[8] I.H. Spinner, J. Cirik, W.F.Graydon, Preparation of Ion-Exchange Resins, Canadian Journal of Chemistry. 32 (1953) 143-152.
[9] The Role of Cross-linking in Ion Exchange Resins (accessed 25 March 2022)
[10] WCP Online, The capacity of ion exchange resin. (accessed 25 March 2022)
[11] Ion Exchange Resin – an overview | ScienceDirect Topics (accessed 25 March 2022)
[12] S.R. Rao, Resource Recovery and Recycling from Metallurgical Wastes, Pages. 1-581 (2006), ISBN: 978-0-08-045131-2, ISSN: 1478-7482.
[13] J. Briffa, E. Sinagra, R. Blundell, Heavy metal pollution in the environment and their toxicological effects on humans, Heliyon. 6 (2020) e04691.
[14] A.V. Singh, N. k. Sharma, A.S. Rathore, Synthesis, characterization and applications of a new cation exchanger tamarind sulphonic acid (TSA) resin, Environmental Technology. 33 (4) (2012) 473-480.
[15] M. Draye, K.R. Czerwinski, A. Favre-Reguillon, J. Foos, A. Guy, M. Lemaire, Selective separation of lanthanides with phenolic resins: extraction behavior and thermal stability, Separation Science and Technology. 35 (8) (2000) 1117-1132.
[16] N. Dumont, A. Favre-Reguillon, B. Dunjic, M. Lemaire, Extraction of Cesium from an alkaline leaching solution of spent catalyst using an Ion-Exchange Column, Separation Science and Technology. 31 (7) (1996) 1001-1010.
[17] K.L. Noyes, N. Charton, Micheline Draye1, K.R. Czerwinski, Synthesis and evaluation of resins for actinide separations, Materials Research Society. 757 (2003) 635-640.
[18] Z. Hubicki, D. Kołodyńska, Selective Removal of heavy metal ions from waters and wastewaters using ion exchange methods, in: A. Kilislioğlu (Eds.), The Edited Volume: Ion Exchange Technologies, IntechOpen, 2012, pp. 193-240.
[19] M.A. Ali, M.A. Rahman, A.M. Shafiqul Alam, Use of EDTA-grafted anion-exchange resin for the separation of selective heavy metal ions, Analytical Chemistry Letters. 3 (3) (2013) 199-207.
[20] G. Al-Enezi, M.F. Hamoda, N. Fawzi, Ion Exchange Extraction of Heavy Metals from Wastewater Sludges, Journal of Environmental Science and Health. A. 39 (2004) 455-464.
[21] R. Kiefer, W.H. Holl, Sorption of heavy metals onto selective Ion-Exchange Resins with aminophosphonate functional groups, Ind. Eng. Chem. Res. 40 (2001) 4570-4576.
[22] M.A. Harmer, Q. Sun, Solid acid catalysis using ion-exchange resins, Appl. Catal. Gen. 221 (2001) 45-62.
[23] S.A. Cavaco, S. Fernandes, M.M. Quina, L.M. Ferreira, Removal of chromium from electroplating industry effluents by ion exchange resins, J. Hazard. Mater. 144 (2007) 634-638.
[24] J. Wang, Z. Wan, Treatment and disposal of spent radioactive ion-exchange resins produced in the nuclear industry, Prog. Nucl. Energy. 78 (2015) 47-55.
[25] J. Paul Chen, M.L. Chua, B. Zhang, Effects of competitive ions, humic acid, and pH on removal of ammonium and phosphorus from the synthetic industrial effluent by ion exchange resins, Waste Manag. 22 (2002) 711-719.
[26] J. Kammerer, R. Carle, D.R. Kammerer, Adsorption and Ion Exchange: Basic principles and their application in food processing, J. Agric. Food Chem. 59 (2011) 22-42.
[27] L. Kisley, J. Chen, A. P. Mansur, B. Shuang, K. Kourentzi, M. Poongavanam, W. Chen, S. Dhamane, R. Willson, C. F. Landes, Unified superresolution experiments and stochastic theory provide mechanistic insight into protein ion-exchange adsorptive separations, App. Phy. Sci. 111 (6) (2014) 2075-2080.
[28] R. F. Schubert and P. H. Ko, Methods used in the analysis of shampoos, J. Soc. Cosmet. Chem. 23 (1972) 887-898.
[29] V. R. Moreira, Y. A. R. Lebron, A. F. S. Foureaux, L. V. de S. Santos, and M. C. S. Amaral, Acid and metal reclamation from mining effluents: Current practices and future perspectives towards sustainability, J. Environ. Chem. Eng. 9 (2021) 105169.
[30] A.B. Junior, D.C.R. Espinosa, J. Vaughan, J.A.S. Tenório, Recovery of scandium from various sources: A critical review of the state of the art and future prospects, Miner. Eng. 172 (2021) 107148.
[31] M. Fomina, G.M. Gadd, Biosorption: current perspectives on concept, definition and application, Bioresour. Technol. 160 (2014) 3-14.