Graphene-Metal Oxides Modified Electrochemical Sensors for Toxic Chemicals

$30.00

Graphene-Metal Oxides Modified Electrochemical Sensors for Toxic Chemicals

L. Vidhya, T. Ramya, S. Vinodha

This chapter discusses the recent progresses in environmental electrochemistry and its wide capabilities and application towards pollution free environment. Various chemicals including agrochemicals, heavy metals, and other toxic materials polluting the environment can either be treated or transformed to non-toxic elements. Environmental protection and incessant development of people’s value of life are found to be the most important areas of the application of electrochemical sensors in future. A sensor, here, is a chemical-play-tool that converts a chemical data like composition, presence of a particular ion, concentration, chemical activity, and partial pressure into a systematically useful signal. Currently, with new challenges and prospects, the electrochemical sensors have new and wide areas of outlook and applications. The electrochemical biosensor is a simple device that measures electronic current either ionic or by change in conductance carried by the bio-electrodes. Generally, carbon materials are widely used as electrode substrates to make different electrodes owing to its soft properties and renewable for exchange of electrons. Befittingly the arrangement of carbon atoms in graphene enhances its promising applications in several fields. On the other hand, nano materials possess good geometric as well as unique mechanical, physical and chemical properties that significantly encourage applications in medicine, electronics, environmental science and biosensors. In this chapter, the application of graphene- ZnO nano composite material is discussed for analysing the toxic chemicals in the environment and biological samples because of its high sensitivity and good reproducibility.

Keywords
Electro Chemical Sensors, Graphene, Metal Oxides, Nano Composites, ZnO, Chemical Pollutants

Published online 8/30/2020, 26 pages

Citation: L. Vidhya, T. Ramya, S. Vinodha, Graphene-Metal Oxides Modified Electrochemical Sensors for Toxic Chemicals, Materials Research Foundations, Vol. 82, pp 125-150, 2020

DOI: https://doi.org/10.21741/9781644900956-5

Part of the book on Graphene-Based Electrochemical Sensors for Toxic Chemicals

References
[1] Jhumi Jain, Pammi Gauba, Heavy metal toxicity-implications on metabolism and health, Int J Pharma Bio Sci, 8(4) (2017) 452-460. https://doi.org/10.22376/ijpbs.2017.8.4.b452-460
[2] Ksenia S. Egorova and Valentine P. Ananikovm, Toxicity of Metal Compounds: Knowledge and Myths, Organometallics, 36 (2017) 4071-4090. https://doi.org/10.1021/acs.organomet.7b00605
[3] A.M. O’Mahony, J. Wang, Nanomaterial-based electrochemical detection of explosives: a review of recent developments, Anal. Methods, 5 (2013) 4296. https://doi.org/10.1039/c3ay40636a
[4] Maduraiveeran Govindhan, Bal-Ram Adhikari and Aicheng Chen, A. Chen, Nanomaterials-based electrochemical detection of chemical contaminants, RSC Adv. 4 2014) 63741. https://doi.org/10.1039/C4RA10399H
[5] JR Windmiller, J Wang, Wearable electrochemical sensors and biosensors: a review, Electroanalysis, 25 (1) (2013) 29-46. https://doi.org/10.1002/elan.201200349
[6] J Ma, D Yuan, K Lin, S Feng, T Zhou, Q Li, Applications of flow techniques in seawater analysis: A review., Trends Environ. Anal. Chem, 10 (2016) 1-10. https://doi.org/10.1016/j.teac.2016.02.003
[7] J.N. Stetter, W.R. Penrose, Y. Sheng, Sensors, chemical sensors, electrochemical sensors, and ECS. J. Electrochem. Soc, (2003)150: S11–S16. https://doi.org/10.1149/1.1539051
[8] E. Bakker, M. Telting-Diaz, Electrochemical sensors, Anal. Chem., 74 (2002) 2781-2800. https://doi.org/10.1021/ac0202278
[9] Iuliana Moldoveanua, Raluca-Ioana Stefan-van Stadena and Jacobus Frederick van Staden, Electrochemical Sensors Based on Nanostructured Materials, Handbook of Nano electrochemistry. 10.1007/978-3-319-15207-3_47-1.
[10] F. Vajedi, H. Dehghani, The characterization of TiO2-reduced graphene oxide nanocomposites and their performance in electrochemical determination for removing heavy metals ions of cadmium(II), lead(II) and copper(II), Mater. Sci. Eng B. 243 (2019) 189–198. https://doi.org/10.1016/j.mseb.2019.04.009
[11] J.M. George, A. Antony, B. Mathew, Metal oxide nanoparticles in electrochemical sensing and bio sensing: a review, Microchimica Acta, 185 (2018) 358. https://doi.org/10.1007/s00604-018-2894-3
[12] Arnab Halder, Minwei Zhang and Qijin Chi, Electrocatalytic Applications of Graphene–Metal Oxide Nano hybrid Materials, Advanced Catalytic Materials – Photocatalysis and Other Current Trends.
[13] A. Farmer and C. T. Campbell, Ceria Maintains, Smaller Metal Catalyst Particles by Strong Metal-Support Bonding, Science, 329, 5994 (2010) pp. 933–936. https://doi.org/10.1126/science.1191778
[14] Georgakilas, V., Otyepka, M., Bourlinos, A. B., Chandra, V., Kim, N., Kemp, K. C., Hobza, P., Zboril, R., Kim, K.S. Functionalization of Graphene: Covalent and Non-Covalent Approaches, Derivatives and Applications, Chem. Rev, 112 (2012) 6156−6214. https://doi.org/10.1021/cr3000412
[15] Georgakilas, V., Tiwari, J., Kemp, K.C., Perman, J., Bourlinos, A., Kim, K.S., Zboril, R. Non-Covalent Functionalization of Graphene and Graphene Oxide for Energy Materials, Bio sensing, Catalytic, and Biomedical Applications. Chem. Rev, 116 (2016) 5464−5519. https://doi.org/10.1021/acs.chemrev.5b00620
[16] Srikanth Ammu, Graphene based chemical sensors, Science Lettters, 4 (2015) 162.
[17] X. Du, I. Skachko, A. Barker, E.Y. Andrei, Approaching ballistic transport in suspended grapheme, Nat. Nanotechnol., 3 (2008) 491. https://doi.org/10.1038/nnano.2008.199
[18] E. Pallecchi, F. Lafont, V. Cavaliere, F. Schopfer, D. Mailly, W. Poirier, A. Ouerghi, High Electron Mobility in Epitaxial Graphene on 4H-SiC (0001) via post-growth annealing under hydrogen, Sci. Rep., 4 (2014) 4558. https://doi.org/10.1038/srep04558
[19] C.L. Weaver, H. Li, X. Luo, X.T. Cui, A graphene oxide/conducting polymer nanocomposite for electrochemical dopamine detection: origin of improved sensitivity and specificity, J. Mater. Chem -B, 2 (2014) 5209. https://doi.org/10.1039/C4TB00789A
[20] K.P. Loh, Q. Bao, G. Eda, M. Chhowalla, Graphene oxide as a chemically tunable platform for optical applications, Nat. Chem., 2 (2010) 1015. https://doi.org/10.1038/nchem.907
[21] X. Sun, Z. Liu, K. Welsher, J.T. Robinson, A. Goodwin, S. Zaric, H. Dai, Nano-Graphene Oxide for Cellular Imaging and Drug Delivery, Nano Res., 1 (2008) 203. https://doi.org/10.1007/s12274-008-8021-8
[22] C.N.R. Rao, K.S. Subrahmanyam, H.S.S.R. Matte, and A. Govindaraj, Graphene: synthesis, functionalization and properties, MOD PHYS LETT B, 25(2011) 427-451. https://doi.org/10.1142/S0217984911025961
[23] V. Dua, S.P. Surwade, S. Ammu, S.R. Agnihotra, S. Jain, K.E. Roberts, S. Park, R.S. Ruoff S.K. Manohar, All-organic vapor sensor using inkjet-printed reduced grapheme oxide, Angew. Chem., 49 (2010) 2154. https://doi.org/10.1002/anie.200905089
[24] Y. Liu, B. Xie, Z. Zhang, Q, Zheng, Z. Xu, Mechanical properties of graphene papers, J MECH PHYS SOLIDS, 60 (4) (2012) 591. https://doi.org/10.1002/anie.200905089
[25] G. Eda, G. Fanchini, M. Chhowalla, Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material, Nat. Nanotechnol, 3 (2008) 270. https://doi.org/10.1038/nnano.2008.83
[26] M.F. El-Kady, V. Strong, S. Dubin, R.B. Kaner, Laser scribing of high-performance and flexible graphene-based electrochemical capacitor, Science, 335 (2012) 1326. https://doi.org/10.1126/science.1216744
[27] M.D. Stoller, S. Park, Y. Zhu, J. An, R.S. Ruoff, Graphene-Based Ultracapacitors, Nano Lett, 8 (2008) 3498. https://doi.org/10.1021/nl802558y
[28] Y. Wang, Z. Shi, Y. Huang, Y. Ma, C. Wang, M. Chen, Y. Chen, Supercapacitor devices based on Graphene materials, J. Phys, Chem.,113 (2009) 13103. https://doi.org/10.1021/jp902214f
[29] Dale A.C. Brownson, Dimitrios K. Kampouris, Craig E. Banks, An overview of graphene in energy production and storage applications, J. Power Sources, 196 (2011) 4873-4885. https://doi.org/10.1016/j.jpowsour.2011.02.022
[30] S. Watcharotone, D.A. Dikin, S. Stan,kovich, R. Piner, I. Jung, G.H.B. Dommett, G. Evmenenko, S.-E. Wu, S.-F. Chen, C.-P. Liu, S.T. Nguyen, R.S. Ruoff, Graphene-silica composite thin films as transparent conductors, Nano. Lett. 7 (2007) 1888. https://doi.org/10.1021/nl070477+
[31] V.C. Tung, L.-M. Chen, M.J. Allen, J.K. Wassei, K. Nelson, R.B. Kaner, Y. Yang, Low-temperature solution processing of graphene-carbon nanotube hybrid materials for high- performance transparent conductors, Nano Lett. 9 (2009) 1949. https://doi.org/10.1021/nl9001525
[32] F. Xia, T. Mueller, Y.-m. Lin, A. Valdes-Garcia, P. Avouris, Ultrafast graphene photodetector, Nat. Nanotechnol, 4 (2009) 839. https://doi.org/10.1038/nnano.2009.292
[33] F. Schwierz, Graphene transistors, Nat. Nanotechnol, 5 (2010) 487. https://doi.org/10.1038/nnano.2010.89
[34] S. Roy, Z. Gao, Nanostructure-based electrical, Nano Today, 4 (4) (2009) 318-334. https://doi.org/10.1016/j.nantod.2009.06.003
[35] C. Chen, J. Hone, Proc. Graphene nanoelectromechanical systems, IEEE 101 (2013) 1766. https://doi.org/10.1109/JPROC.2013.2253291
[36] Y. Liu, X. Dong, P. Chen, Biological and chemical sensors based on graphene materials, Chem. Soc. Rev, 41 (2012) 2283. https://doi.org/10.1039/C1CS15270J
[37] S. MacNaughton, S. Sonkusale, S. Surwade, S. Ammu, S. Manohar, S. MacNaughton, S. Sonkusale, S. Surwade, S. Ammu, S. Manohar, IEEE Sensors (2010) 894.
[38] Ksenia S. Egorova and Valentine P. Ananikov, Toxicity of Metal Compounds: Knowledge and Myths, Organometallics, 36 (2017) 4071-4090. https://doi.org/10.1021/acs.organomet.7b00605
[39] Woolley, A.A. Guide to Practical Toxicology: Evaluation, Prediction, and Risk, 2nd ed.; Informa Healthcare USA: New York, 2008. https://doi.org/10.1201/9781420043150
[40] A Textbook of Modern Toxicology; Hodgson, E., Ed.; Wiley: Hoboken, New Jersey, 2010.
[41] J.F. Shen, B. Yan, M. Shi, H.W. Ma, N. Li, M.X. Ye, One step hydrothermal synthesis of TiO2-reduced graphene oxide sheets, J. Mater. Chem, 21(2011) 3415. https://doi.org/10.1039/c0jm03542d
[42] Wang ZY, Huang BB, Dai Y, Liu YY, Zhang XY, Qin XY, Wang JP, Zheng ZK, Cheng HF. Crystal facets controlled synthesis of graphene@TiO2 nanocomposites by a one-pot hydrothermal process, CRECF4, 14 (2012) 1687. https://doi.org/10.1039/C1CE06193C
[43] Changyuan Hu , Tiewen Lu , Fei Chen & Rongbin Zhang, A brief review of graphene–metal oxide composites synthesis and applications in photocatalysis, J. Chinese. Adv. Mater. Soc., 1910 (2013) 21-39. http://dx.doi.org/10.1080/22243682.2013.771917
[44] Wen-Yi Zhou, Jinyun Liu, Jieyao Song, Jinjin Li, Jinhuai Liu, Xing-Jiu Huang, Surface-Electronic-State-Modulated, Single-Crystalline (001) TiO2 Nanosheets for Sensitive Electrochemical Sensing of Heavy-Metal Ions, Anal. Chem, 89 (6) (2017) 3386–3394. https://doi.org/10.1021/acs.analchem.6b04023
[45] X. Han, Q. Kuang, M. Jin, Z. Xie, L. Zheng, Synthesis of titania nanosheets with a high percentage of exposed (001) facets and related photocatalytic properties, J. Am. Chem. Soc., 131 (2009) 3152-3153. https://doi.org/10.1021/ja8092373
[46] Yan Wei, Chao Gao, Fan-Li Meng, Hui-Hua Li, Lun Wang, Jin-Huai Liu, Xing-Jiu Huang, SnO2/Reduced Graphene Oxide Nanocomposite for the Simultaneous Electrochemical Detection of Cadmium(II), Lead(II), Copper(II) and Mercury(II): An Interesting Favorable Mutual Interference, J. Phys. Chem.C, 16 (2012) 1034-1041. https://doi.org/10.1021/jp209805c
[47] Wei Liu, Preparation of a zinc oxide-reduced graphene oxide nanocomposite for the determination of Cadmium(II), Lead(II), Copper(II), and Mercury(II) in water, Int. J. Electrochem. Sci., 2 (2017) 5392-5403. https://doi.org/10.20964/2017.06.06
[48] World Health Organization (WHO), Guidelines for drinking water quality, Sixty-first Meeting, Rome, June 10-19 2003
[49] Sohee Lee, Jiseop Oh, Dongwon Kim and Yuanzhe Piao, A sensitive electrochemical sensor using an iron oxide/graphene composite for the simultaneous detection of heavy metal ions, Talanta. https://doi.org/10.1016/j.talanta.2016.07.034
[50] Zhi-Liang Wu, Cheng-Kun Li, Jin-Gang Yu, Xiao-Qing Chen, MnO2/Reduced Graphene Oxide Nanoribbons: Facile hydrothermal preparation and their application in amperometric detection of hydrogen peroxide, SENSOR ACTUAT B-CHEM, 239 (2017) 544-552. https://doi.org/10.1016/j.snb.2016.08.062
[51] Solomon W. Leung, Maedeh Mozneb, James C.K. Lai, An ultra-sensitive Sol-Gel bio composite electrode sensor for cyanide detection, Sensors & Transducers, 191(8) 2015, 114-119.
[52] S. Mozneb, J.C.K. Lai, S.W. Leung, Cyanide detection by highly modified Sol-Gel bio composite sensor, in Proceeding of the NSTI, Nanotechnology Conference & Expo, Diagnostics & Imaging, Washington, D.C., 3 (3) (2015) 155-158.
[53] Hallaj, R., Haghighi, N. Photo electrochemical amperometric sensing of cyanide using a glassy carbon electrode modified with graphene oxide and titanium dioxide nanoparticles, Microchim Acta, 184, (2017) 3581-3590. https://doi.org/10.1007/s00604-017-2366-1
[54] Tanvir Arfin, Stephy N. Rangarim Graphene oxide–ZnO nanocomposite modified electrode for the detection of phenol, ANAL. METHODS. https://doi.org/10.1039/C7AY02650A
[55] Yaling Tian, eihong Deng, Yiyong Wu, Junhua Li, Jun Liu, Guangli Li, Quanguo H, MnO2 nanowires-decorated reduced graphene oxide modified glassy carbon electrode for sensitive determination of bisphenol, J. Electrochem, 167 (2020) 046514. https://doi.org/10.1149/1945-7111/ab79a7
[56] Junyu Lei, Xiaofeng Lu , Wei Wang , Xiujie Bian , Yanpeng Xue , Ce Wang and Lijuan Li , Fabrication of MnO2/graphene oxide composite nanosheets and their application in hydrazine detection RSC Adv., 2 (2012) 2541. https://doi.org/10.1039/c2ra01065h
[57] S. E. Baghbamidi, H. Beitollahi, S. Tajik. Graphene oxide nano-sheets/ferrocene derivative modified carbon paste electrode as an electrochemical sensor for determination of hydrazine. Anal. Bioanal. Electrochem.,6 (2014) 634.
[58] Z. Yang, Q. Sheng, S. Zhang, X. Zheng, J. Zheng, One-pot synthesis of Fe3O4/polypyrrole/graphene oxide nanocomposites for electrochemical sensing of hydrazine, Microchim. Acta. 184 (2017) 2219–2226. https://doi.org/10.1007/s00604-017-2197-0
[58] Dipa Dutta, Sudeshna Chandra, Akshaya K. Swain, Dhirendra Bahadu, SnO2 Quantum dots-reduced graphene oxide composite for enzyme-free ultrasensitive electrochemical detection of urea, ANA. CHEM., 86 (12) (2014), 5914-5921. https://doi.org/10.1021/ac5007365
[59] Ming Yan Wang, Jun Rao Huang, Meng Wang, Dong E Zhang, Jun Chen, Electrochemical nonenzymatic sensor based on CoO decorated reduced graphene oxide for the simultaneous determination of Carbofuran and Carbaryl in fruits and vegetables. Food Chem, 151 (2014) 191-197. https://doi.org/10.1016/j.foodchem.2013.11.046
[60] Raja Nehru, Praveen Kumar Gopi and Shen-Ming Chen, Enhanced sensing of hazardous 4-nitrophenol by a graphene oxide–TiO2 composite: Environmental pollutant monitoring applications, RSC. https://doi.org/10.1039/C9NJ06176B
[61] M.K. Alam, M.M. Rahman, M. Abbas, S.R. Torati, A.M. Asiri, D. Kim, C.G. Kim, Ultra-sensitive 2-nitrophenol detection based on reduced graphene oxide/ZnO nanocomposites, J. Electro anal. Chem. 788 (2017) 66–73. https://doi.org/10.1016/j.jelechem.2017.02.004