MOF-Derived Nanocarbons: Synthesis, Properties, and Applications
Boris I. Kharisov, Cesar Maximo Oliva González, Thelma Serrano Quezada, Oxana V. Kharissova, Yolanda Peña Mendez
Nanocarbons, derived from the metal-organic frameworks (MOFs), are reviewed. These nanomaterials represent different carbon allotropes with presence of initial metals in elemental or oxidized forms, depending on the calcination conditions. The main route for obtaining MOF-derived nanocarbons is the pyrolysis at temperatures in the range of 700-1000 oC. The formed nanoporous materials possess useful properties, allowing them to be used for catalytic purposes, in adsorption processes, supercapacitors and solution of environmental problems, among other uses.
Metal-Organic Frameworks, Nanocarbons, Bimetallic Nanocarbons, Catalysis, Pyrolysis
Published online 6/30/2019, 22 pages
Citation: Boris I. Kharisov, Cesar Maximo Oliva González, Thelma Serrano Quezada, Oxana V. Kharissova, Yolanda Peña Mendez, MOF-Derived Nanocarbons: Synthesis, Properties, and Applications, Materials Research Foundations, Vol. 53, pp 235-256, 2019
Part of the book on Metal-Organic Framework Composites
 H. Wang, Q. Zhu, R. Zou, X. Qiang, Metal-Organic Frameworks for Energy-Related Applications, Chem., 4.1 (2017), 52–80.
 K. Shen, X. Chen, J. Chen,Y. Li, Development of MOF-Derived Carbon-Based Nanomaterials for Efficient Catalysis, ACS Catalysis, 6.9 (2016), 5887–5903. https://doi.org/10.1021/acscatal.6b01222
 P.C. Rae, Y. S. Jae, K.R. Patent 20,130,031,926 (A), (2013).
 Q. Ren, H. Wang, X. Lu, Y.X. Tong, G.R. Li, Recent Progress on MOF-Derived Heteroatom-Doped Carbon-Based Electrocatalysts for Oxygen Reduction Reaction, Advanced Science, 5.3 (2018), 1700515. https://doi.org/10.1002/advs.201700515
 L. Lux, K. Williams, S. Ma, Heat-Treatment of Metal-Organic Frameworks for Green Energy Applications, CrystEngComm, 17.1 (2015), 10–22. https://doi.org/10.1039/c4ce01499e
 M. Yang, X. Hu, Z. Fang, L. Sun, Z. Yuan, S. Wang, W. Hong, X. Chen, D. Yu, Bifunctional MOF-Derived Carbon Photonic Crystal Architectures for Advanced Zn–Air and Li–S Batteries: Highly Exposed Graphitic Nitrogen Matters, Advanced Functional Materials, 27.36 (2017), 1–9. https://doi.org/10.1002/adfm.201770210
 X. Li, J. Zhang, Y. Han, M. Zhu, S. Shang, W. Li, MOF-Derived Various Morphologies of N-Doped Carbon Composites for Acetylene Hydrochlorination, Journal of Materials Science, 53.7 (2018), 4913–26. https://doi.org/10.1007/s10853-017-1951-3
 B. Chen, G. Ma, D. Kong, Y. Zhu, Y. Xia, Atomically Homogeneous Dispersed ZnO/N-Doped Nanoporous Carbon Composites with Enhanced CO2uptake Capacities and High Efficient Organic Pollutants Removal from Water, Carbon, 95 (2015), 113–24. https://doi.org/10.1016/j.carbon.2015.08.015
 W. Zhang, Z.Y. Wu, H.L. Jiang, S.H. Yu, Nanowire-Directed Templating Synthesis of Metal-Organic Framework Nanofibers and Their Derived Porous Doped Carbon Nanofibers for Enhanced Electrocatalysis, Journal of the American Chemical Society, 136.41 (2014), 14385-14388. https://doi.org/10.1021/ja5084128
 B. Ding, J. Wang, Z. Chang, G. Xu, X. Hao, L. Shen, H. Dou, X. Zhang, Self-Sacrificial Template Synthesis of Mixed-Valence-State Cobalt Nanomaterials with High Catalytic Activities for Colorimetric Detection of Glutathione, Sensors and Actuators, B: Chemical, 254 (2018), 329–36. https://doi.org/10.1016/j.snb.2017.07.104
 R. Chen, T. Zhao, T. Tian, S. Cao, P. R. Coxon, K. Xi, D. J. Fairen, R. Vasant, R. Cheetham, K. Anthony, Graphene-Wrapped Sulfur/Metal Organic Framework-Derived Microporous Carbon Composite for Lithium Sulfur Batteries, APL Materials, 2.12 (2014), 124109. https://doi.org/10.1063/1.4901751
 H. Wu, S. Wei, L. Zhang, R. Xu, H. Hng, X. Lou, Embedding Sulfur in MOF-Derived Microporous Carbon Polyhedrons for Lithium-Sulfur Batteries, Chemistry – A European Journal, 19.33 (2013), 10804–8. https://doi.org/10.1002/chem.201301689
 A. Banerjee, K. Upadhyay, D. Puthusseri, V. Aravindan, S. Madhavi, S. Ogale, MOF-Derived Crumpled-Sheet-Assembled Perforated Carbon Cuboids as Highly Effective Cathode Active Materials for Ultra-High Energy Density Li-Ion Hybrid Electrochemical Capacitors (Li-HECs), Nanoscale, 6.8 (2014), 4387–94. https://doi.org/10.1039/c4nr00025k
 K. Cendrowski, W. Kukulka, T. Kedzierski, S. Zhang, Poly (Vinylidene Fluoride) and Carbon Derivative Structures from Eco-Friendly MOF-5 for Supercapacitor Electrode Preparation with Improved Electrochemical Performance, Nanomaterials, 8.11, (2018), 890. https://doi.org/10.3390/nano8110890
 T. Segakweng, N. Musyoka, J. Ren, P. Crouse, H. Langmi, , Comparison of MOF-5- and Cr-MOF-Derived Carbons for Hydrogen Storage Application, Research on Chemical Intermediates, 42.5 (2016), 4951–61. https://doi.org/10.1007/s11164-015-2338-1
 A. Li, Y. Tong, B. Cao, H. Song, Z. Li, X. Chen, J. Zhou, G. Chen, H. Luo,, MOF-Derived Multifractal Porous Carbon with Ultrahigh Lithium-Ion Storage Performance, Scientific Reports, 7 (2017), 1–8. https://doi.org/10.1038/srep40574
 C.Y. Lee, U.S. Patent 20,180,214,849. (2018).
 P. Haijun, L. Xiaoming, N. Jiliang, C. Yuepeng, W.O. Patent 107,492,637. (2017).
 H. Xu, S. Zhou, L. Xiao, H. Wang, S. Li, Q. Yuan, Fabrication of a Nitrogen-Doped Graphene Quantum Dot from MOF-Derived Porous Carbon and Its Application for Highly Selective Fluorescence Detection of Fe3+, Journal of Materials Chemistry C, 3.2 (2015), 291–97. https://doi.org/10.1039/c4tc01991a
 F. Zheng, G. Xia, Y. Yang, O. Chen, MOF-Derived Ultrafine MnO Nanocrystals Embedded in a Porous Carbon Matrix as High-Performance Anodes for Lithium-Ion Batteries, Nanoscale, 7.21 (2015), 9637–45. https://doi.org/10.1039/c5nr00528k
 S. Liu, J. Zhou, Z. Cai, G. Fang, Y. Cai, A. Pan, S. Liang, Nb2O5 Quantum Dots Embedded in MOF Derived Nitrogen-Doped Porous Carbon for Advanced Hybrid Supercapacitor Applications, Journal of Materials Chemistry A, 4.45 (2016), 17838–47. https://doi.org/10.1039/c6ta07856g
 H. Li, L. Chi, C. Yang, L. Zhang, F. Yue, J. Wang, MOF Derived Porous Co@C Hexagonal-Shaped Prisms with High Catalytic Performance, Journal of Materials Research, 31.19 (2016), 3069–77. https://doi.org/10.1557/jmr.2016.314
 H. Sung, M. Arumugam, Self-Templated Synthesis of Co- and N-Doped Carbon Microtubes Composed of Hollow Nanospheres and Nanotubes for Efficient Oxygen Reduction Reaction, Small, 13.11 (2017), 1–8. https://doi.org/10.1002/smll.201603437
 Y. Zhou, Y. Chen, L. Cao, J. Lu, H. Jiang, Conversion of a Metal-Organic Framework to N-Doped Porous Carbon Incorporating Co and CoO Nanoparticles: Direct Oxidation of Alcohols to Esters, Chemical Communications, 51.39 (2015), 8292–95. https://doi.org/10.1039/c5cc01588j
 L. Andrew, C. Hsuan, J. Bo, Multi-Functional MOF-Derived Magnetic Carbon Sponge, Journal of Materials Chemistry A, 4.35 (2016), 13611–25.
 N. Torad, M. Hu, S. Ishihara, H. Sukegawa, A. Belik, M. Imura, K. Ariga, Y. Sakka, Direct Synthesis of MOF-Derived Nanoporous Carbon with Magnetic Co Nanoparticles toward Efficient Water Treatment, Small, 10.10 (2014), 2096–2107. https://doi.org/10.1002/smll.201302910
 L. Torad, M. Hu, S. Ishihara, H. Sukegawa, A. Belik, M. Imura, K. Ariga, Y. Sakka, Y. Yamauchi, A Novel Metal – Organic Framework Route to Embed Co Nanoparticles into Multi-Walled Carbon Nanotubes for Effective Oxygen Reduction in Alkaline Media. Catalysts, 7.12, (2017), 364. https://doi.org/10.3390/catal7120364
 X. Liu, X. Quan, Fe-MOF Derived Ferrous Hierarchically Porous Carbon Used as EF Cathode for PFOA Degradation, 2017 International Conference on Environmental Pollution and Public Health, EPPH 2017, (2017), 9–14. https://doi.org/10.4236/gep.2017.56002
 E. C. Walter, T. Beetz, M. Y. Sfeir, L. E. Brus, Crystalline Graphite from an Organometallic Solution-Phase Reaction, Journal of the American Chemical Society, 128.49 (2006), 15590–91. https://doi.org/10.1021/ja0666203
 Z. Hasan, D. Cho, I. Nam, C. Chon, H. Song, Preparation of calcined zirconia-carbon composite from metal organic frameworks and its application to adsorption of crystal violet and salicylic acid. Materials, 9.4, (2016),261. https://doi.org/10.3390/ma9040261
 S. Liang, W. Qian, M. Zhonglei, L. Ying, X. Juan, W.O. Patent 107,578,927. (2018).
 S. Wu, Y. Zhu, Y. Huo, Y. Luo, L. Zhang, Y. Wan, B. Nan, L. Cao, Bimetallic Organic Frameworks Derived CuNi/Carbon Nanocomposites as Efficient Electrocatalysts for Oxygen Reduction Reaction, Science China Materials, 60.7 (2017), 654–63. https://doi.org/10.1007/s40843-017-9041-0
 H. Sung, J. Michael, M. Arumugam, 1D Co- and N-Doped Hierarchically Porous Carbon Nanotubes Derived from Bimetallic Metal Organic Framework for Efficient Oxygen and Tri-Iodide Reduction Reactions, Advanced Energy Materials, 7.7 (2017), 1–9. https://doi.org/10.1002/aenm.201601979
 Q. Gan, K. Zhao, S. Liu, Z. He, MOF-Derived Carbon Coating on Self-Supported ZnCo2O4–ZnO Nanorod Arrays as High-Performance Anode for Lithium-Ion Batteries, Journal of Materials Science, 52.13 (2017), 7768–80. https://doi.org/10.1007/s10853-017-1043-4
 Z. Li, L. Yin, MOF-Derived, N-Doped, Hierarchically Porous Carbon Sponges as Immobilizers to Confine Selenium as Cathodes for Li-Se Batteries with Superior Storage Capacity and Perfect Cycling Stability, Nanoscale, 7.21 (2015), 9597–9606. https://doi.org/10.1039/c5nr00903k
 H. Wang, X. Zhang, Y. Wang, G. Quan, X. Han, J. Yan, Facile Synthesis of Magnetic Nitrogen-Doped Porous Carbon from Bimetallic Metal–Organic Frameworks for Efficient Norfloxacin Removal, Nanomaterials, 8.9 (2018), 664. https://doi.org/10.3390/nano8090664
 C. Watcharop, A. Katsuhiko, Y. Yusuke, A New Family of Carbon Materials: Synthesis of MOF-Derived Nanoporous Carbons and Their Promising Applications, Journal of Materials Chemistry A, 1.1 (2013), 14–19. https://doi.org/10.1039/c2ta00278g
 Y. Min, F. Kam, Z. George, Synthesis and Applications of MOF-Derived Porous Nanostructures, Green Energy & Environment, 2.3 (2017), 218–45.
 S. Fardindoost, S. Hatamie, A. Zad, F. Astaraei, Hydrogen Sensing Properties of Nanocomposite Graphene Oxide/Co-Based Metal Organic Frameworks (Co-MOFs@GO), Nanotechnology, 29.1 (2017), 7. https://doi.org/10.1088/1361-6528/aa9829
 W. Zhiling, C. Yu, Y. Xiaofeng, L. Zhilian, Z. Luyi, W.O. Patent 107,576,714. (2018).
 G. Cai, W. Zhang, L. Jiao, S. Yu, H. Jiang, Template-Directed Growth of Well-Aligned MOF Arrays and Derived Self-Supporting Electrodes for Water Splitting, Chem, 2.6 (2017), 791–802. https://doi.org/10.1016/j.chempr.2017.04.016
 N. Torad, Y. Li, S. Ishihara, K. Ariga, Y. Kamachi, H. Lian, H. Hamoudi, Y. Sakka, W. Chaikittisilp, K. Wu, Y. Yamauchi, MOF-Derived Nanoporous Carbon as Intracellular Drug Delivery Carriers, Chemistry Letters, 43.5 (2014), 717–19. https://doi.org/10.1246/cl.131174
 L. Xiao, R. Xu, Q. Yuan, F. Wang, Highly Sensitive Electrochemical Sensor for Chloramphenicol Based on MOF Derived Exfoliated Porous Carbon, Talanta, 167. January (2017), 39–43. https://doi.org/10.1016/j.talanta.2017.01.078
 W. Li, S. Hu, X. Luo, Z. Li, X. Sun, Confined Amorphous Red Phosphorus in MOF‐Derived N‐Doped Microporous Carbon as a Superior Anode for Sodium‐Ion Battery, Advanced Materials, 29.16 (2017), 1605820. https://doi.org/10.1002/adma.201605820
 C. Sun, Q. Dong, J. Yang, Z. Dai, J. Lin, P. Chen, Metal–organic Framework Derived CoSe2 nanoparticles Anchored on Carbon Fibers as Bifunctional Electrocatalysts for Efficient Overall Water Splitting, Nano Research, 9.8 (2016), 34–43. https://doi.org/10.1007/s12274-016-1110-1
 A. Banerjee, R. Gokhale, S. Bhatnagar, J. Jog, M. Bhardwaj, MOF Derived Porous Carbon-Fe3O4 Nanocomposite as a High Performance, Recyclable Environmental Superadsorbent, Journal of Materials Chemistry, 22.37 (2012), 19694–99. https://doi.org/10.1039/c2jm33798c
 H. Wu, B. Xia, L. Yu, X. Yu, X. Lou, Porous Molybdenum Carbide Nano-Octahedrons Synthesized via Confined Carburization in Metal-Organic Frameworks for Efficient Hydrogen Production, Nature Communications, 6 (2015), 6512. https://doi.org/10.1038/ncomms7512