Adsorption and ion exchange: basic principles and their application in food processing


Adsorption and ion exchange: basic principles and their application in food processing

Suvardhan Kanchi, Myalownkosi I Sabela, Krishna Bisetty, Shakeel Ahmed

This chapter provides a critical review for a wide range of ion-exchange chromatography applications which is an integral part of our food processing industry. The characteristics of ion exchange chromatography are reviewed with particular emphasis on the basic principle and its column materials using state-of-the-art analytical instrumentation coupled with different detectors for analysis.

Adsorption, Chromatography, Anion-Exchange Chromatography, Cation-Exchange Chromatography, Food Applications

Published online 4/25/2017, 22 pages
Copyright © 2016 by the author(s)
Published under license by Materials Research Forum LLC., Millersville PA, USA

Citation: Suvardhan Kanchi, Myalownkosi I Sabela, Krishna Bisetty, Shakeel Ahmed, ‘Adsorption and ion exchange: basic principles and their application in food processing’, Materials Research Foundations, Vol. 15, pp 277-298, 2017


The article was published as article 10 of the book Applications of Adsorption and Ion Exchange Chromatography in Waste Water Treatment

[1] P. R. Haddad, P. E. Jackson, Journal of Chromatography Library-Volume 46 Ion Chromatography. Amsterdam: Elsevier Science (1990).
[2] F. Harm, A. Rumpler, 5th International Congress on Pure and Applied Chem. 59 (1903).
[3] R. Gans, German Pat No. 197,111 (1906).
[4] P. De Brunn, German. Pat No. 270, 324 (1914).
[5] P. N. Engel, German. Pat No. 583, 974 (1933).
[6] H. Fuertig, F. Wolf, U. Headicke, M. Weber, H. Knoll, German (East), Pat. No. 55, 326, April (1967), Chem. Abstr., 67, 83511z, (1967).
[7] K. A. Kraus, H. O. Phillips, T. A. Carlson, J. S. Johnson, International Conference on Peaceful use of Atomic Energy 2nd Conference, Geneva, 28, 3 (1958).
[8] C. B. Amphlett, P. Eaton, L.A. McDonald, A. J. Miller, Synthetic inorganic ion- exchange materials-IV: Equilibrium studies with monovalent cations and zirconium phosphate, J. Inorg. Nucl. Chem., 26(2) (1964) 297-304.
[9] M. W. Michael U.S. Pat No.2, 543,666, (1951).
[10] R. F. Boyer, U.S. Pat No.2, 500, 149, (1950).
[11] D. F. Bradley, A. Rich, The fractionation of ribonucleic acid on ECTEOLA-Cellulose anion exchangers, J. Am. Chem. Soc., 78 (1956) 5898-5902.
[12] W.C. Bauman, G.B. Heusted, U.S Pat. No.2, 614, 099, (1952).
[13] E. L. McMaster, Tolksmith, U.S. Pat. No.2, 764, 560,(1956).
[14] R. Ramaswamy, PhD. Thesis University of Poona, (1970).
[15] O. Liebknecht, U.S. Pat. Nos. 2,191,060, (1940), 2,206, 007, (1940).
[16] O. Liebknecht, US. Pat. No.2, 378, 307, (1945).
[17] Council of Scientific and Industrial Research, Indian Pat. No. 47,446, (1954).
[18] D. Cozzi, P.G. Desideri, L. Lepri, G. Ciantelli, Alginic acid, a new thin layer material, J. Chromatgr. 35(3) (1968) 396-404.
[19] Information on ca/~cchieh/cact applychem /alsilicate. accessed on 30/6/2016.
[20] A. S. Behrman, H. Gustafson, Removal of Fluorine from Water A Development in the Use of Tricalcium Phosphate, Ind. Eng. Chem. 30 (1938) 1011-1013.
[21] Q.-C. Chen, S.-F. Mou, X.-P. Hou, Z.-M. Ni, Simultaneous determination of caffeine, theobromine and theophylline in foods and pharmaceutical preparations by using ion chromatography, Anal. Chim. Acta 371 (1998) 287-296.
[22] H. Lee, V. Luiz de MeloSilva, Y. Liu, D. Barile, Quantification of carbohydrates in whey permeate products using high-performance anion-exchange chromatography with pulsed amperometric detection, J. Dairy Sci. 98 (2015) 7644–7649.
[23] Q.-C. Chen, J. Wang, Simultaneous determination of artificial sweeteners, preservatives, caffeine, theobromine and theophylline in food and pharmaceutical preparations by ion chromatography, J. Chromatogr. A 937 (2001) 57-64.
[24] S.J. Gerberding, C. H. Byers, Preparative ion-exchange chromatography of proteins from dairy whey, J. Chromatogr. A 808 (1998) 141-151.
[25] M. Amigo-Benavent, V. I. Athanasopoulos, M. Dolores del Castillo, Ion exchange chromatographic conditions for obtaining individual subunits of soybean β-conglycinin, J. Chromatogr. B 878 (2010) 2453–2456.
[26] X.-B. Xu, D.-B. Liu, X. M. Guo, S.-J. Yu, P. Yu, Improvement of sugar analysis sensitivity using anion-exchange chromatography-electrospray ionisation mass spectrometry with sheath liquid interface, J. Chromatogr. A 1366 (2014) 65-72.
[27] C. Gu´erin-Dubiard, M. Pasco, A. Hietanen, A. Quiros del Bosque, F. Naua, T. Croguennec, Hen egg white fractionation by ion-exchange chromatography, J. Chromatogr. A 1090 (2005) 58-67.
[28] D.L.A. Fernandes, C.M. Silva, A.M.R.B. Xavier, D.V. Evtuguin, Fractionation of sulphite spent liquor for biochemical processing using ion exchange resins, J. Biotechnol. 162 (2012) 415-421.
[29] E. Leeb, A. Holder, T. Letzel, S. C. Cheison,U. Kulozik, J. Hinrichs, Fractionation of dairy based functional peptides using ion-exchange membrane adsorption chromatography and cross-flow electro membrane filtration, Int. Dairy J. 38 (2014) 116-123.
[30] A.A. Krokidis, N.C. Megoulas, M.A. Koupparis, EDTA determination in pharmaceutical formulations and canned foods based on ion chromatography with suppressed conductimetric detection, Anal. Chim. Acta 535 (2005) 57-63.
[31] T. T. Christison, J. S. Rohrer, Direct determination of free cyanide in drinking water by ion chromatography with pulsed amperometric detection, J. Chromatogr. A 1155 (2007) 31-39.
[32] H.-B. Zhu, Y.-C. Fan, Y.-L. Qian, H.-F. Tang, Z. Ruan, D.-H. Liu, H. Wang, Determination of spices in food samples by ionic liquid aqueous solution extraction and ion chromatography, Chinese Chem. Lett. 25 (2014) 465-468.
[33] A. Kakou, N. C. Megoulas, M. A. Koupparis, Determination of l-carnitine in food supplement formulations using ion-pair chromatography with indirect conductimetric detection, J. Chromatogr. A 1069 (2005) 209-215.
[34] G. Favaro, P. Pastore, G. Saccani, S. Cavalli, Determination of biogenic amines in fresh and processed meatby ion chromatography and integrated pulsed amperometric detection on Au electrode, Food Chem. 105 (2007) 1652-1658.
[35] X.-M. Jiang, Y.-M. Lu, C.-P. Tan, Y.-L., B. Cui, Combination of aqueous two-phase extraction and cation-exchange chromatography: New strategies for separation and purification of alliin from garlic powder, J. Chromatogr. B 957 (2014) 60-67.
[36] D. A. Omana, J. Wang, J. Wu, Co-extraction of egg white proteins using ion-exchange chromatography from ovomucin-removed egg whites, J. Chromatogr. B 878 (2010) 1771-1776.


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